Soft-x-ray magnetic-circular-dichroism study of the colossal-magnetoresistance spinel Fe0.5Cu0.5Cr2S4
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DEB, Aniruddha, MIZUMAKI, Masaichiro, MURO, Takayuki, SAKURAI, Yoshiharu, TSURKAN, Vladimir. Soft-x-ray magnetic-circular-dichroism study of the colossal-magnetoresistance spinel Fe0.5Cu0.5Cr2S4. In: Physical Review B - Condensed Matter and Materials Physics, 2003, vol. 68, p. 0. ISSN 1098-0121. DOI: https://doi.org/10.1103/PhysRevB.68.014427
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Physical Review B - Condensed Matter and Materials Physics
Volumul 68 / 2003 / ISSN 1098-0121 /ISSNe 1550-235X

Soft-x-ray magnetic-circular-dichroism study of the colossal-magnetoresistance spinel Fe0.5Cu0.5Cr2S4

DOI:https://doi.org/10.1103/PhysRevB.68.014427

Pag. 0-0

Deb Aniruddha12, Mizumaki Masaichiro1, Muro Takayuki1, Sakurai Yoshiharu1, Tsurkan Vladimir3
 
1 Japan Synchrotron Radiation Research Institute, Sayo, Hyogo,
2 Lawrence Berkeley National Laboratory,
3 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 4 iulie 2023


Rezumat

We have investigated the electronic and magnetic structure of the colossal magnetoresistive Cr-based spinel Fe0.5Cu0.5Cr2S4 employing magnetic circular dichroism (MCD) of core level absorption (x-ray absorption spectroscopy) spectra in the soft x-ray region. The results here clearly establish that Fe is in the formal trivalent state (Fe3+) in this compound, resolving previous controversies. The Cr 2p and Fe 2p x-ray absorption and MCD spectra shows that the magnetic moment of the tetrahedrally coordinated Fe3+ are aligned antiparallel to those of the octahedrally coordinated Cr3+. The observed Cu 2p MCD spectra show existence of very small magnetic moments (<0.20μB) on the copper sites. The magnetic moments at the Fe and the Cr sites have been obtained based on the magneto-optical sum rules. The results are consistent with the band structure calculation based on the full potential augmented plane wave method.

Cuvinte-cheie
absorption, article, circular dichroism, electromagnetic field, magnetism, spectrum, X ray crystallography

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<dc:creator>Deb, A.</dc:creator>
<dc:creator>Mizumaki, M.</dc:creator>
<dc:creator>Muro, T.</dc:creator>
<dc:creator>Sakurai, Y.</dc:creator>
<dc:creator>Ţurcan, V.V.</dc:creator>
<dc:date>2003-07-25</dc:date>
<dc:description xml:lang='en'><p>We have investigated the electronic and magnetic structure of the colossal magnetoresistive Cr-based spinel Fe<sub>0.5</sub>Cu<sub>0.5</sub>Cr<sub>2</sub>S<sub>4</sub>&nbsp;employing magnetic circular dichroism (MCD) of core level absorption (x-ray absorption spectroscopy) spectra in the soft x-ray region. The results here clearly establish that Fe is in the formal trivalent state (Fe<sup>3+</sup>) in this compound, resolving previous controversies. The Cr 2p and Fe 2p x-ray absorption and MCD spectra shows that the magnetic moment of the tetrahedrally coordinated Fe<sup>3+</sup>&nbsp;are aligned antiparallel to those of the octahedrally coordinated Cr3+. The observed Cu 2p MCD spectra show existence of very small magnetic moments (&lt;0.20&mu;<sub>B</sub>) on the copper sites. The magnetic moments at the Fe and the Cr sites have been obtained based on the magneto-optical sum rules. The results are consistent with the band structure calculation based on the full potential augmented plane wave method.</p></dc:description>
<dc:identifier>10.1103/PhysRevB.68.014427</dc:identifier>
<dc:source>Physical Review B - Condensed Matter and Materials Physics  () 0-0</dc:source>
<dc:subject>absorption</dc:subject>
<dc:subject>article</dc:subject>
<dc:subject>circular dichroism</dc:subject>
<dc:subject>electromagnetic field</dc:subject>
<dc:subject>magnetism</dc:subject>
<dc:subject>spectrum</dc:subject>
<dc:subject>X ray crystallography</dc:subject>
<dc:title>Soft-x-ray magnetic-circular-dichroism study of the colossal-magnetoresistance spinel Fe0.5Cu0.5Cr2S4</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
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