Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
156 0 |
SM ISO690:2012 PERRY IV, John J., KRAVTSOV, Victor, MCMANUS, Gregory J., ZAWOROTKO, Michael. Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra. In: Journal of the American Chemical Society, 2007, vol. 129, pp. 10076-10077. ISSN 0002-7863. DOI: https://doi.org/10.1021/ja0734952 |
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Journal of the American Chemical Society | ||||||
Volumul 129 / 2007 / ISSN 0002-7863 /ISSNe 1520-5126 | ||||||
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DOI:https://doi.org/10.1021/ja0734952 | ||||||
Pag. 10076-10077 | ||||||
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Rezumat | ||||||
A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm. |
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Cuvinte-cheie EMTREE drug terms 1, 3 benzenedicarboxylate, benzene derivative, Carboxylic acid, Coordination compound, cupric ion, dicarboxylic acid, Dimethyl sulfoxide, hydrogen, metal ion, nanoball, nanoparticle, oxygen, polyhedra, Pyridine, unclassified drug EMTREE medical terms article, chemical structure, covalent bond, cross linking, crystal structure, crystallography, nanoanalysis, node and spacer method, quadruple covalent, rhombihexahedron, synthesis, technique |
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