Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra
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PERRY IV, John J., KRAVTSOV, Victor, MCMANUS, Gregory J., ZAWOROTKO, Michael. Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra. In: Journal of the American Chemical Society, 2007, vol. 129, pp. 10076-10077. ISSN 0002-7863. DOI: https://doi.org/10.1021/ja0734952
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Journal of the American Chemical Society
Volumul 129 / 2007 / ISSN 0002-7863 /ISSNe 1520-5126

Bottom up synthesis that does not start at the bottom: Quadruple covalent cross-linking of nanoscale faceted polyhedra

DOI:https://doi.org/10.1021/ja0734952

Pag. 10076-10077

Perry IV John J.1, Kravtsov Victor2, McManus Gregory J.1, Zaworotko Michael1
 
1 University of South Florida,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
 
Disponibil în IBN: 30 iunie 2023


Rezumat

A novel 3D metal-organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm. 

Cuvinte-cheie
EMTREE drug terms 1, 3 benzenedicarboxylate, benzene derivative, Carboxylic acid, Coordination compound, cupric ion, dicarboxylic acid, Dimethyl sulfoxide, hydrogen, metal ion, nanoball, nanoparticle, oxygen, polyhedra, Pyridine, unclassified drug EMTREE medical terms article, chemical structure, covalent bond, cross linking, crystal structure, crystallography, nanoanalysis, node and spacer method, quadruple covalent, rhombihexahedron, synthesis, technique