Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
316 0 |
SM ISO690:2012 CHIŞCA, Diana, CROITOR, Lilia, COROPCEANU, Eduard, PETUHOV, Oleg, BACA, Svetlana, KRAMER, Karl W, LIU, Shi-Xia, DECURTINS, Silvio, RIVERA-JACQUEZ, Hector J., MASUNOV, Artem, FONARI, Marina. From pink to blue and back to pink again: Changing the Co(II) ligation in a two-dimensional coordination network upon desolvation. In: CrystEngComm, 2016, vol. 18, pp. 384-389. ISSN 1466-8033. DOI: https://doi.org/10.1039/c5ce01581b |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
CrystEngComm | |
Volumul 18 / 2016 / ISSN 1466-8033 | |
|
|
DOI:https://doi.org/10.1039/c5ce01581b | |
Pag. 384-389 | |
Rezumat | |
Heating of a pink two-dimensional Co(ii) coordination network {[Co2(μ2-OH2)(bdc)2(S-nia)2(H2O)(dmf)]·2(dmf)·(H2O)}n (1) built from 1,4-benzenedicarboxylic acid (H2bdc) residues and thionicotinamide (S-nia) ligands initiates a single-crystal-to-single-crystal transition accompanied by removal of both coordinated and co-crystallized solvents. In the dry blue form, [Co(bdc)(S-nia)]n (dry-1), the Co(ii) centers changed from an octahedral to a square pyramidal configuration. |
|
Cuvinte-cheie Metal-organic frameworks, Schläfli Symbol, Coordination polymer |
|
|