Jahn-Teller effect in molecular electronics: Quantum cellular automata

Tsukerblat Boris S.; Palii Andrew; Clemente-Juan Juan; Coronado Eugenio

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2024-02-22 03:37

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TSUKERBLAT, Boris S., PALII, Andrew, CLEMENTE-JUAN, Juan, CORONADO, Eugenio. Jahn-Teller effect in molecular electronics: Quantum cellular automata. In: Journal of Physics: Conference Series, Ed. 23, 27 august - 1 septembrie 2016, Tartu. Bristol, United Kingdom: Institute of Physics Publishing, 2017, Ediția 23, Vol. 833, pp. 1-16. ISSN 17426588. DOI: https://doi.org/10.1088/1742-6596/833/1/012002

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Journal of Physics: Conference Series
Ediția 23, Vol. 833, 2017

Masa rotundă "23rd International Symposium on the Jahn-Teller Effect: Vibronic Coupling and Electron-Phonon Interaction in Molecules and Crystals 2016"
23, Tartu, Estonia, 27 august - 1 septembrie 2016

Jahn-Teller effect in molecular electronics: Quantum cellular automata

DOI:https://doi.org/10.1088/1742-6596/833/1/012002

Pag. 1-16

Tsukerblat Boris S.¹, Palii Andrew²³, Clemente-Juan Juan⁴, Coronado Eugenio⁴

¹ Ben-Gurion University of the Negev,
² Institute of Problems of Chemical Physics, Chernogolovka, Moscow Region,
³ Institute of Applied Physics, Academy of Sciences of Moldova,
⁴ Instituto de Ciencia Molecular, Universidad de Valencia

Disponibil în IBN: 11 iunie 2022

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The article summarizes the main results of application of the theory of the Jahn-Teller (JT) and pseudo JT effects to the description of molecular quantum dot cellular automata (QCA), a new paradigm of quantum computing. The following issues are discussed: 1) QCA as a new paradigm of quantum computing, principles and advantages; 2) molecular implementation of QCA; 3) role of the JT effect in charge trapping, encoding of binary information in the quantum cell and non-linear cell-cell response; 4) spin-switching in molecular QCA based on mixed-valence cell; 5) intervalence optical absorption in tetrameric molecular mixed-valence cell through the symmetry assisted approach to the multimode/multilevel JT and pseudo JT problems.

Cuvinte-cheie
Adiabatic approximation, electron transfer, Jahn-Teller effect, magnetic polyoxometalates, mixed-valency, molecular electronics, quantum computing, quantum-dot cellular automata, vibronic interactions

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