| Conţinutul numărului revistei |
| Articolul precedent |
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 SM ISO690:2012KORCHAGIN, Denis, GUREEV, Ya, YURIEVA, Elena, SHILOV, Gennadii, AKIMOV, Alexander, MISOCHKO, Eugenii, MORGUNOV, Roman, ZAKHAROV, Konstantin, VASILIEV, Alexander, PALII, Andrew, LOHMILLER, Thomas, HOLLDACK, Karsten, ALDOSHIN, Serghei. Field-induced single-ion magnet based on a quasi-octahedral Co(ii) complex with mixed sulfur-oxygen coordination environment. In: Dalton Transactions, 2021, nr. 39(50), pp. 13815-13822. ISSN 1477-9226. DOI: https://doi.org/10.1039/d1dt02413b |
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  Dalton Transactions |
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| Numărul 39(50) / 2021 / ISSN 1477-9226 /ISSNe 1477-9234 | |
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| DOI:https://doi.org/10.1039/d1dt02413b | |
| Pag. 13815-13822 | |
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Synthesis and characterization of structure and magnetic properties of the quasi-octahedral complex (pipH2)[Co(TDA)2] 2H2O (I), (pipH22+ = piperazine dication, TDA2- = thiodiacetic anion) are described. X-ray diffraction studies reveal the first coordination sphere of the Co(ii) ion, consisting of two chelating tridentate TDA ligands with a mixed sulfur-oxygen strongly elongated octahedral coordination environment. SQUID magnetometry, frequency-domain Fourier-transform (FD-FT) THz-EPR spectroscopy, and high-level ab initio SA-CASSCF/NEVPT2 quantum chemical calculations reveal a strong "easy-plane"type magnetic anisotropy (D ≈ +54 cm-1) of complex I. The complex shows field-induced slow relaxation of magnetization at an applied DC field of 1000 Oe. |
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Dublin Core Export
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc='http://purl.org/dc/elements/1.1/' xmlns:oai_dc='http://www.openarchives.org/OAI/2.0/oai_dc/' xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xsi:schemaLocation='http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd'> <dc:creator>Korchagin, D.V.</dc:creator> <dc:creator>Gureev, Y.E.</dc:creator> <dc:creator>Yurieva, E.A.</dc:creator> <dc:creator>Shilov, G.V.</dc:creator> <dc:creator>Akimov, A.V.</dc:creator> <dc:creator>Misochko, E.Y.</dc:creator> <dc:creator>Morgunov, R.B.</dc:creator> <dc:creator>Zakharov, K.V.</dc:creator> <dc:creator>Vasiliev, A.N.</dc:creator> <dc:creator>Palii, A.V.</dc:creator> <dc:creator>Lohmiller, T.</dc:creator> <dc:creator>Holldack, K.</dc:creator> <dc:creator>Aldoshin, S.M.</dc:creator> <dc:date>2021-10-21</dc:date> <dc:description xml:lang='en'><p>Synthesis and characterization of structure and magnetic properties of the quasi-octahedral complex (pipH2)[Co(TDA)2] 2H2O (I), (pipH22+ = piperazine dication, TDA2- = thiodiacetic anion) are described. X-ray diffraction studies reveal the first coordination sphere of the Co(ii) ion, consisting of two chelating tridentate TDA ligands with a mixed sulfur-oxygen strongly elongated octahedral coordination environment. SQUID magnetometry, frequency-domain Fourier-transform (FD-FT) THz-EPR spectroscopy, and high-level ab initio SA-CASSCF/NEVPT2 quantum chemical calculations reveal a strong "easy-plane"type magnetic anisotropy (D ≈ +54 cm-1) of complex I. The complex shows field-induced slow relaxation of magnetization at an applied DC field of 1000 Oe.</p></dc:description> <dc:identifier>10.1039/d1dt02413b</dc:identifier> <dc:source>Dalton Transactions 50 (39) 13815-13822</dc:source> <dc:title>Field-induced single-ion magnet based on a quasi-octahedral Co(ii) complex with mixed sulfur-oxygen coordination environment</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> </oai_dc:dc>
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