(Ag x Cu 1-x ) 2 ZnSn(S,Se) 4 Thin Films Prepared by Spray Pyrolysis: The Influence of the Ag Concentration
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DERMENJI, Lazari, BRUC, Leonid, GURIEVA, Galina, GUK, Maxim, CURMEI, Nicolai, SHERBAN, Dormidont, SIMASHKEVICH, Aleksey, SCHORR, S., ARUSHANOV, Ernest. (Ag x Cu 1-x ) 2 ZnSn(S,Se) 4 Thin Films Prepared by Spray Pyrolysis: The Influence of the Ag Concentration. In: 2018 IEEE 7th World Conference on Photovoltaic Energy Conversion: WCPEC 2018 - A Joint Conference of 45th IEEE PVSC, 28th PVSEC and 34th EU PVSEC, 10-15 iunie 2018, Waikoloa, Hawaii. New Jersey, SUA: Institute of Electrical and Electronics Engineers Inc., 2018, Ediția a 7-a, pp. 798-801. ISBN 978-153868529-7. DOI: https://doi.org/10.1109/PVSC.2018.8547312
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2018 IEEE 7th World Conference on Photovoltaic Energy Conversion
Ediția a 7-a, 2018
Conferința "7th IEEE World Conference on Photovoltaic Energy Conversion"
Waikoloa, Hawaii, Statele Unite ale Americii, 10-15 iunie 2018

(Ag x Cu 1-x ) 2 ZnSn(S,Se) 4 Thin Films Prepared by Spray Pyrolysis: The Influence of the Ag Concentration

DOI:https://doi.org/10.1109/PVSC.2018.8547312

Pag. 798-801

Dermenji Lazari1, Bruc Leonid1, Gurieva Galina2, Guk Maxim1, Curmei Nicolai1, Sherban Dormidont1, Simashkevich Aleksey1, Schorr S.23, Arushanov Ernest1
 
1 Institute of Applied Physics,
2 Helmholtz-Centre Berlin for Materials and Energy,
3 Freie Universitat Berlin, Institut fur Geologische Wissenschaften
 
 
Disponibil în IBN: 3 iunie 2021


Rezumat

Thin films of (Ag x Cu 1-x ) 2 ZnSn(S,Se) 4 (ACZTSSe), with x = 0.05 - 0.20, were deposited using the spray pyrolysis method, with subsequent annealing in S + Se atmosphere. Investigation of the chemical composition, structural properties and Raman scattering spectroscopy allowed to conclude that for thin films with up to 15 % of Ag concentration there is stable the formation of the solid solutions of ACZTSSe, while in the thin film with 20 % Ag strong compositional and phase inhomogeneities were found. Investigation of the electrical transport properties showed their insignificant change with increasing the Ag concentration up to 15 %.

Cuvinte-cheie
Electrical properties, GIXRD, kesterite, Raman scattering spray pyrolysis thin films