Application of NMR technique in the elucidation of marine natural compounds
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CIAVATTA, Maria-Letizia. Application of NMR technique in the elucidation of marine natural compounds . In: Chemistry Journal of Moldova, 2011, nr. 2(6), pp. 9-12. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 2(6) / 2011 / ISSN 1857-1727 /ISSNe 2345-1688

Application of NMR technique in the elucidation of marine natural compounds

Pag. 9-12

Ciavatta Maria-Letizia
 
 
 
Disponibil în IBN: 30 noiembrie 2013


Rezumat

The topic of the seminar held in the Institute of Chemistry, Academy of Sciences of Moldova on 30th September in the frame of the joint Moldo-Italian seminar “New frontiers in natural product chemistry”, concerned the use of NMR techniques in the elucidation of natural products. Step by step, two marine compounds (Fulvyne C and Tritoniopsin A) belonging to different chemical classes have been analyzed, by using suitable NMR experiments. This powerful technique allowed the elucidation of compounds as fulvynes, long chain polyacetylenes with the same functional groups but differently located in the chain, as well as tritoniopsins, cyclic diterpenes with a new skeleton, providing further information on their relative and absolute stereochemistry.

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the use of NMR techniques in the elucidation of natural products. Step by step, two marine compounds (Fulvyne C
and Tritoniopsin A) belonging to different chemical classes have been analyzed, by using suitable NMR experiments.
This powerful technique allowed the elucidation of compounds as fulvynes, long chain polyacetylenes with the same
functional groups but differently located in the chain, as well as tritoniopsins, cyclic diterpenes with a new skeleton,
providing further information on their relative and absolute stereochemistry.
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