Magnetic properties of copper(II) complexes with aminoguanizone of pyruvic acid
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DONICĂ, Ioana. Magnetic properties of copper(II) complexes with aminoguanizone of pyruvic acid. In: Physical Methods in Coordination and Supramolecular Chemistry, 27 septembrie - 1 octombrie 2006, Chişinău. Chisinau, Republic of Moldova: 2006, XVII, p. 121. ISBN 978-9975-62-066-6.
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Physical Methods in Coordination and Supramolecular Chemistry
XVII, 2006
Conferința "The XV-th International Conference Physical Methods in Coordination and Supramolecular Chemistry : The XVII-th Reading in memory of Acad. A.Ablov"
Chişinău, Moldova, 27 septembrie - 1 octombrie 2006

Magnetic properties of copper(II) complexes with aminoguanizone of pyruvic acid


Pag. 121-121

Donică Ioana
 
Institute of Chemistry
 
 
Disponibil în IBN: 10 iunie 2020


Rezumat

Earlier in laboratory of bioinorganic chemistry of the Institute of Chemistry of the Academy of Sciences of Moldova the systematic purposeful synthesis, investigation of properties and structure particularities of coordination compounds on the basis of new polydentate multifunctional hydrazones as well as the study of their biological activity were carried out [1]. In continuation of previous research, 8 new coordination compounds of Cu(II) with aminoguanizone of pyruvic acid (H2paag) were synthesized [2]. X-ray analysis of these complexes revealed, that most of these compounds have dimeric or polymeric structure [3]. As a rule in such complexes there is an exchange magnetic interaction. One of the methods, allowing to elucidate the presence of the magnetic exchange interaction, is the measurement of the magnetic susceptibility. We measured magnetic properties of synthesized complexes at room temperature for compounds Cu(paag)·nH2O, CuX(Hpaag), where Х = CH3COO-, SO4 2-, NO3 -, Cl-, Br-. The obtained values of the effective magnetic moment of these complexes vary from 1,63 to 2,19 ВМ, which are in a good concordance with the analogous values for other copper compounds without the magnetic exchange interaction. The temperature dependence of a magnetic susceptibility of polymeric bromide complex, Cu(Hpaag)·Br [3] (see fig.), measured in the range of temperatures 110-291 K, follows to the Curie-Weiss law, specifying thus the absence of exchange magnetic interaction between paramagnetic copper(II) ions. The obtained data don’t contradict the EPR spectra results [2].