Literature searches, based on the use of SciFinder Scholar database showed for the keywords „catalysed decomposition of biomass” and „biofuels” more than 500 literature references, among them 150 publications devoted to catalysed decomposition of biomass. For this reason, research on new catalysts compounds are very important and highly topical themes. These studies connecting the new methodology of the synthesis of ceramic materials and new methods for the preparation of synthesis gas free of sulfur and phosphorus, which will be used for the preparation of the appropriate fractions of fuels. Material properties, especially absorption and catalytic largely depend on their structure. The condition and mode of formation compounds and concentration and temperature ranges of their existence explains the phase diagrams. Therefore, the study in described project will be based on basic research include: synthesis of alloy phase diagram determination, determine their crystal and electron structure and the study of catalytic properties of these materials. This project focuses on the original experimental work aimed at obtaining ceramics, combine them with the material of the botanical origin (grain and straw of cereals, starchy crops) and investigate the effect of the above ceramics on thermal decomposition of "biomass". Full physicochemical analysis for received system was carried out using thermal analysis DSC / TG and TGA / SDTA / QMS to the selection process for obtaining the best possible conditions for carbonizate and qualitative composition of the gases as promising materials for the synthesis of second-generation fuels in the near future. The study of the ceramic material will be show the potential structural changes in the used as a potential catalyst systems. The main objective of this project is the development of a new generation of ceramic materials subsidized by Li ions and the study of these oxides in catalytic processes. Implementation of the proposed project increased library of "knowledge" on the ceramic materials subsidized by Li ions which formed on the basis of sintering metal oxides or hydroxides and their use as catalysts in the preparation of quality control of the synthesis gas from the char material or botanical origin. Investigated ceramic materials are new, not described in the chemical literature concerning to the compounds in which the presence of Li provides a convenient opportunity to induce catalytic property and ensures the appearance of physical and chemical properties useful when used as substrates derivatives obtained in Chemistry "new materials" (in particular of the "catalyzed") and new substances for controlling the process of pyrolysis of biomass.