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<cfTitle cfLangCode='EN' cfTrans='o'>Electric-Field Control of Magnetic and Polarizability Properties of Cyanide-Bridged Fe&ndash;Co Clusters</cfTitle>
<cfKeyw cfLangCode='EN' cfTrans='o'>cobalt; Electron transfer; iron; magnetic properties; Moessbauer spectroscopy; Polarizability</cfKeyw>
<cfAbstr cfLangCode='EN' cfTrans='o'><p>We present a new microscopic approach for the description of the effects of an external direct current (dc) electric field on the magnetic, polarizability, and spectroscopic characteristics of molecular crystals containing cyanide-bridged Fe&ndash;Co clusters as structural units. In addition to the interaction with the electric field, the model allows for metal&ndash;metal electron transfer, intracluster magnetic exchange, and long-range electron-deformational interactions, which are taken into account within the mean-field approach. The external electric field gives a unique possibility to manipulate the polarizability, magnetic, and spectroscopic characteristics of cyanide-bridged Fe&ndash;Co clusters.</p></cfAbstr>
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