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Ultima descărcare din IBN: 2022-04-08 12:45 |
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539.2:538.9 (1) |
Proprietăţile şi structura sistemelor moleculare (224) |
Fizica materiei condensate. Fizica solidului (349) |
SM ISO690:2012 CIOBANU, Marina, TSIULYANU , Dumitru. Effect of aging, temperature, and ambient gases on the complex impedance of As2Te13Ge8S3 glassy films. In: Moldavian Journal of the Physical Sciences, 2021, nr. 2(20), pp. 151-162. ISSN 1810-648X. DOI: https://doi.org/10.53081/mjps.2021.20-2.06 |
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Moldavian Journal of the Physical Sciences | |||||||
Numărul 2(20) / 2021 / ISSN 1810-648X /ISSNe 2537-6365 | |||||||
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DOI:https://doi.org/10.53081/mjps.2021.20-2.06 | |||||||
CZU: 539.2:538.9 | |||||||
Pag. 151-162 | |||||||
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The work is focused on the application of the impedance spectroscopy method to provide evidence and study the effects of aging, temperature, and gas adsorption in chalcogenide-based thin films. The experiments are carried out with thin films of glassy quaternary composition As2Te13Ge8S3 in a wide frequency range at different temperatures under different environmental conditions, in particular, either dry or wet air or their mixtures with NO2 or CO2. It is found that aging has a significant effect on the impedance spectra of Pt–As2Te13Ge8S3–Pt functional structures, which make evidence for the presence of substantial spatial and compositional disordering. This effect can be stabilized by the post-preparation annealing of the sample. The effect of temperature on impedance spectra consists in a variation in the both real and imaginary parts of impedance that appear to be extremely sensitive to adsorptive processes. Adsorption of nitrogen dioxide results in a significant frequency-dependent decrease in the impedance parameters, which is attributed to an effective “strong” chemisorption process due to the interaction of "odd" electrons of NO2 molecules with lone pair electrons of chalcogen atoms. The effect of water vapors leads only to an increase in the real part of impedance, while the imaginary part abruptly decreases; this fact is attributed to a “weak” form of chemisorption. The effect of carbon dioxide on the impedance spectra is attributed to the physical adsorption of CO2 molecules. This effect is weak; however, it is reversible and clearly observed even at room temperature. |
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Cuvinte-cheie Chalcogenides, Impedance, aging, adsorption, NO2, CO2, calcogenuri, impedanță, îmbătrânire, adsorbţie, NO2, CO2 |
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