Sulphitation of wine products with solution prepared of tartaric acid and potassium sulphite
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2023-05-11 09:25
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COVACI, Ecaterina, PRIDA, Ivan. Sulphitation of wine products with solution prepared of tartaric acid and potassium sulphite. In: Achievements and perspectives of modern chemistry, 9-11 octombrie 2019, Chişinău. Chisinau, Republic of Moldova: Tipografia Academiei de Ştiinţe a Moldovei, 2019, p. 87. ISBN 978-9975-62-428-2.
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Achievements and perspectives of modern chemistry 2019
Conferința "International Conference "Achievements and perspectives of modern chemistry""
Chişinău, Moldova, 9-11 octombrie 2019

Sulphitation of wine products with solution prepared of tartaric acid and potassium sulphite


Pag. 87-87

Covaci Ecaterina1, Prida Ivan2
 
1 Technical University of Moldova,
2 ÎTŞ „OenoConsulting” SRL
 
 
Disponibil în IBN: 5 noiembrie 2019


Rezumat

Sulphitation of wine products is a routine process widely used in the wine industry at various stages of production and regulated by normative and technological documents of wine products manufacturing. Disposing of the needs and technological possibilities of industrial enterprises, sulphitation process of wine is carried out using sulphur dioxide as sulphur source: sulphuric acid, native sulphur, liquefied sulphur dioxide and salts of sulphuric acid (meta - and sulphites) [1]. The sulphitation process of wine products using of salts of sulphites - potassium sulphite (K2S2O5, E 224) has gained a large spread not only in craft winemaking but also in large wineries. At the same time, the basic disadvantage of this process is the exogenous enrichment of wine products with potassium ions, and the reduction of mass concentration of total titratable acids, which leads to the risk of crystalline instability resulting from the precipitation of tartaric salts thus, limiting the range of use of this process at the first stages of the manufacture of the wine products [2]. Under laboratory conditions, a process for the sulphitation of wine products has been developed by reducing the risks of crystalline instability at all stages of their production, with the use of potassium sulphite solutions. The process provides a prior preparation of a mixture of 100 g/dm3 potassium sulfite solution and tartaric acid of 300 g/dm3 solution at rapport 2:1 (by volume ratio) with intense stirring. According to the results, the quantitative equilibrium of precipitation is reached at a quantity of 0.3315 mol of the corresponding reactant species and at the value of 0.9995 molar ratio (Figure).Figure. Dynamics of mass concentration of potassium ions remaining in model solution. The prepared solution, based on potassium sulphite and tartaric acid, is used for the sulphitation into wine products, after the pre-separation of the formed precipitate, at all stages of their production. The described process was granted as national patent BOPI no. 952 of 2015. Effectiveness of the selected agent described the preservation of crystalline stability (no tartaric precipitate) and the value of saturation temperature remained constant in the samples. References