Structure and electrical properties of electroactive hybrid polymer composites doped with ionic liquids
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IURZHENKO, M., MAMUNYA, Yevgen, BOITEUX, G., SERGHEI, A., SVERDLIAKOVS‘KA, O., SHTOMPEL, V., CHERVAKOV, O., LEBEDEV, E.. Structure and electrical properties of electroactive hybrid polymer composites doped with ionic liquids. In: Materials Science and Condensed Matter Physics, Ed. 7, 16-19 septembrie 2014, Chișinău. Chișinău, Republica Moldova: Institutul de Fizică Aplicată, 2014, Editia 7, p. 109.
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Materials Science and Condensed Matter Physics
Editia 7, 2014
Conferința "Materials Science and Condensed Matter Physics"
7, Chișinău, Moldova, 16-19 septembrie 2014

Structure and electrical properties of electroactive hybrid polymer composites doped with ionic liquids


Pag. 109-109

Iurzhenko M.1, Mamunya Yevgen1, Boiteux G.2, Serghei A.2, Sverdliakovs‘ka O.3, Shtompel V.1, Chervakov O.3, Lebedev E.1
 
1 Institute of Macromolecular Chemistry of the NAS of Ukraine, Kyiv,
2 Université Lyon,
3 Ukrainian State University of Chemical Technology
 
 
Disponibil în IBN: 27 februarie 2019


Rezumat

Different structural organizations of electroactive hybrid polymers (EPM) including ion conducting phase were found depending on the doping way. The doping leads to destruction of the mineral phase with the simultaneous formation of new crystalline structures due to MS/IL reactions. Contrariwise, synthesis of EPM based on UO and ILs results in amorphous grain-oriented structural organization and formation of the ion conducting cluster with the DC conductivity level σDC ~ 10-3- 10-4 S/cm, AC conductivity level σ΄ ~ 10-2-10-3 S/cm and permittivity ε΄ ~ 105-106 taken at 103 Hz (by the results of BDS, Im and cyclic VA spectroscopy).