Crystal structures of {N-prop-2-en-1-YL-N'-[1-(pyridin-2-yl)-ethylidene]carbamohydrazonothioato}-(2,2’-bipyridine)copper(II) and {N-prop-2-en-1-yl-N'-[1-(pyridin-2-yl)ethylidene]carbamo-hydrazonothioato}-(1,10-phenanthroline)copper(II) nitrates
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GRAUR, Vasilii О., TSAPKOV, Victor I., PETRENKO, Peter A., CHUMAKOV, Yurii, GULYA, Aurelian. Crystal structures of {N-prop-2-en-1-YL-N'-[1-(pyridin-2-yl)-ethylidene]carbamohydrazonothioato}-(2,2’-bipyridine)copper(II) and {N-prop-2-en-1-yl-N'-[1-(pyridin-2-yl)ethylidene]carbamo-hydrazonothioato}-(1,10-phenanthroline)copper(II) nitrates. In: Materials Science and Condensed Matter Physics, Ed. 9, 25-28 septembrie 2018, Chișinău. Chișinău, Republica Moldova: Institutul de Fizică Aplicată, 2018, Ediția 9, p. 142.
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Materials Science and Condensed Matter Physics
Ediția 9, 2018
Conferința "International Conference on Materials Science and Condensed Matter Physics"
9, Chișinău, Moldova, 25-28 septembrie 2018

Crystal structures of {N-prop-2-en-1-YL-N'-[1-(pyridin-2-yl)-ethylidene]carbamohydrazonothioato}-(2,2’-bipyridine)copper(II) and {N-prop-2-en-1-yl-N'-[1-(pyridin-2-yl)ethylidene]carbamo-hydrazonothioato}-(1,10-phenanthroline)copper(II) nitrates

CZU: 546+539.2+54:615.12

Pag. 142-142

Graur Vasilii О.1, Tsapkov Victor I.1, Petrenko Peter A.2, Chumakov Yurii23, Gulya Aurelian1
 
1 Moldova State University,
2 Institute of Applied Physics,
3 Gebze Institute of Technology
 
Proiecte:
 
Disponibil în IBN: 4 februarie 2019


Rezumat

It was found that some of copper coordination compounds with thiosemicarbazide derivatives possess of biological activity. It is known that the presence of different amines in the inner sphere of complexes affects on the biological properties of coordination compounds. Therefore, it is important to study the cooper coordination compounds containing the bidentate amines such as 2,2'-bipyridine (2,2'-Bpy) and 1,10-phenanthroline (1,10-Phen) in the inner sphere.  The aim of this work is the determination of structural properties of hydrates of {N-prop-2-en-1-yl-N'-[1-(pyridin-2-yl)-ethylidene]carbamohydrazonothioato}-(2,2'-bipyridine)copper nitrate [Cu(2,2'-Bpy)L]NO3·H2O (I) and {N-prop-2-en-1-yl-N'-[1-(pyridin-2-yl)ethylidene]carbamo-hydrazonothioato}-(1,10-phenanthroline)copper nitrate [Cu(1,10-Phen)L]NO3·H2O (II). In both complexes the geometry of five-coordinated central atom is approximated by distorted square pyramid where the fifth position is occupied by one of nitrogen atoms of 2,2'-bipyridine or 1,10-phenanthroline.