The solid-state inclusion complex between the mono-anion of calix[4]arene and protonated diamino-bicycloundecane
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SHKURENKO, Oleksandr, PERRET, Florent, SIGAUD, Katia, LEYDIER, Antoine, JEBORS, Said, COLEMAN, Anthony, SUWINSKA, Kinga. The solid-state inclusion complex between the mono-anion of calix[4]arene and protonated diamino-bicycloundecane. In: Chemistry Journal of Moldova, 2009, nr. 2(4), pp. 89-93. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 2(4) / 2009 / ISSN 1857-1727 /ISSNe 2345-1688

The solid-state inclusion complex between the mono-anion of calix[4]arene and protonated diamino-bicycloundecane

Pag. 89-93

Shkurenko Oleksandr, Perret Florent, Sigaud Katia, Leydier Antoine, Jebors Said, Coleman Anthony, Suwinska Kinga
 
 
 
Disponibil în IBN: 2 decembrie 2013


Rezumat

Diamino-bicycloundecane mono-deprotonates H-calix[4]arene and the solid-structure of the resulting salt has been determined by X-ray crystallography. Two different complexes are present in the structure with the Diamino-bicycloundecane cation held in the calix[4]arene cavity by CH-p interactions. In the packing there is a hydrogen-bonded polymeric chain. Both the complexes formed layered structures with differing inter-layer distances.

Cuvinte-cheie
Calix[n]arenes, Mono-anionic, Diamino-Bicycloundecane,

X-ray Crystallography, structure