Synthesis, structure and investigation of germanium(IV) and copper(II) complexes with malic acid and 1,10’-phenanthroline
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2024-03-28 13:47
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546 (505)
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SEIFULLINA, Inna, MARTSINKO, Elena, CHEBANENKO, Elena, AFANASENKO, Eleonora, DYAKONENKO, Viktoriya, SHISHKINA, Svitlana. Synthesis, structure and investigation of germanium(IV) and copper(II) complexes with malic acid and 1,10’-phenanthroline. In: Chemistry Journal of Moldova, 2017, nr. 2(12), pp. 28-33. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 2(12) / 2017 / ISSN 1857-1727 /ISSNe 2345-1688

Synthesis, structure and investigation of germanium(IV) and copper(II) complexes with malic acid and 1,10’-phenanthroline

CZU: 546

Pag. 28-33

Seifullina Inna1, Martsinko Elena1, Chebanenko Elena1, Afanasenko Eleonora1, Dyakonenko Viktoriya2, Shishkina Svitlana23
 
1 Odesa I.I.Mechnikov National University,
2 National Academy of Science of Ukraine,
3 V.N.Karazin Kharkiv Natsonal University
 
Disponibil în IBN: 28 decembrie 2017


Rezumat

Two crystalline compounds of germanium(IV) with malic acid (H3Mal) and 1,10’-phenanthroline (phen) - [Ge(HMal)2(phen)]·phen·2H2O (1) and [CuCl(phen)2][Ge(OH)(HMal)2] (2) were synthesized for the first time and characterized by elemental analysis, IR spectroscopy and thermogravimetric analysis. Using single crystal X-ray diffraction, two different forms of germanium were elucidated: Ge4+ (1) and hydrolyzed GeOH3+ (2) with a distorted octahedron and pyramid surrounding geometry, respectively.  

Cuvinte-cheie
germanium(IV) compound, 10’-phenanthroline,

malic acid, 1, copper(II) complex, structure.