Removal of methylene blue by adsorption onto retama raetam plant: kinetics and equilibrium study
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BADIS, Dalila, BENMAAMAR, Zoubir, BENKORTBI, Othmane, BOUTOUMI, Houcine, HAMITOUCHE, Houria, AGGOUN, Amele. Removal of methylene blue by adsorption onto retama raetam plant: kinetics and equilibrium study. In: Chemistry Journal of Moldova, 2016, nr. 2(11), pp. 74-83. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2016.11(2).10
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Chemistry Journal of Moldova
Numărul 2(11) / 2016 / ISSN 1857-1727 /ISSNe 2345-1688

Removal of methylene blue by adsorption onto retama raetam plant: kinetics and equilibrium study
DOI: https://doi.org/10.19261/cjm.2016.11(2).10
CZU: 543.51

Pag. 74-83

Badis Dalila1, Benmaamar Zoubir2, Benkortbi Othmane1, Boutoumi Houcine2, Hamitouche Houria2, Aggoun Amele2
 
1 University of Dr Yahia Fares,
2 University of Blida1, Soumaa
 
Proiecte:
 
Disponibil în IBN: 26 decembrie 2016


Rezumat

The feasibility of using medicinal plants species Retama raetam as a low cost and an eco-friendly adsorbent for the adsorption of cationic dye methylene blue from simulated aqueous solution has been investigated. Adsorption kinetics of methylene blue onto Retama raetam plants was studied in a batch system. The effects of pH and contact time were examined. The methylene blue maximum adsorption occurred at pH 8 and the lowest adsorption occurred at pH 2. The apparent equilibrium was reached after 120 min. Optimal experimental conditions were determined. Adsorption modelling parameters for Freundlich and Langmuir isotherms were determined and, based on R2, various error distribution functions were evaluated as well. Adsorption isotherm was best described by non linear Freundlich isotherm model. Thermodynamic studies show that adsorption was spontaneous and exothermic. For determining the best-fi t-kinetic adsorption model, the experimental data were analyzed by using pseudo-fi rst-order, pseudo-second-order, pseudo-third-order, Esquivel, and Elovich models. Linear regressive and non-linear regressive method was used to obtain the relative parameters. The statistical functions were estimated to fi nd the suitable method that fi t better the experimental data. Both methods were appropriate for obtaining the parameters. The linear pseudo-second-order (type 9 and type 10) models were the best to fi t the equilibrium data. The present work showed that plant Retama raetam can be used as a low cost adsorbent for the removal of methylene blue from water.

Cuvinte-cheie
Retama raetam,

methylene blue, removal, modelling, adsorption