| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 |
 1027 9 |
| Ultima descărcare din IBN: 2023-06-01 14:41 |
| Căutarea după subiecte similare conform CZU |
| 546-3+544.1+66 (1) |
| Chimie anorganică (450) |
| Structura chimică a materiei (98) |
| Tehnologie chimică. Industrii chimice și înrudite (1500) |
 SM ISO690:2012MIKURIYA, Masahiro, SCHUMACHER, Melissa, KAWANO, Chinatsu, AKIHARA, Takahiro, ONO, Kenta, YOSHIOKA, Daisuke, SAKIYAMA, Hiroshi, HANDA, Makoto. Dinuclear nickel(ii) pivalate with μ-AQUA and DI-μ-Pivalato bridges showing a ferromagnetic interaction. In: Chemistry Journal of Moldova, 2014, nr. 2(9), pp. 62-66. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2014.09(2).09 |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
| Chemistry Journal of Moldova | ||||||
| Numărul 2(9) / 2014 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
|
||||||
| DOI:https://doi.org/10.19261/cjm.2014.09(2).09 | ||||||
| CZU: 546-3+544.1+66 | ||||||
| Pag. 62-66 | ||||||
|
||||||
 Descarcă PDF |
||||||
| Rezumat | ||||||
Abstract. Dinuclear nickel(II) complex, [Ni2{O2CC(CH3)3}4(OH2){HO2CC(CH3)3}4] (1), was synthesized and characterized by elemental analysis, IR and UV-Vis-NIR spectroscopy, and temperature dependence of magnetic susceptibilities (4.5—300 K). Single-crystal X-ray crystallography revealed a dinuclear core with μ-aqua and di-μ-pivalato bridges having monodentate pivalato and monodentate pivalic acid molecules. Magnetic data analysis showed a ferromagnetic interactions between the two nickel atoms with g = 2.251, J = 2.78 cm−1, D = 3.75 cm–1, and
tip = 184 x 10–6 cm3 mol–1; g = 2.253, J = 2.73 cm−1, D = –3.26 cm–1, and tip = 176 x 10–6 cm3 mol–1. |
||||||
| Cuvinte-cheie nickel complex, dinuclear complex, ferromagnetic interaction, magnetic property |
||||||
|
|
|
|
