Ten mixed-ligand one-(1D) and two-dimensional (2D) Cu(ii) coordination polymers that include: {[Cu(SiF₆)(4-pyaoH)₄]·dmf·0.5H₂O}_n (1), {[Cu(mal)(4-pyaoH)₂]·dmf}_n (2), {[Cu(mal)₂](4-pyaoH₂)₂}_n (3), [Cu(adi)(3-pyaoH)₂(H₂O)]_n (4), [Cu(adi)(3-pyaoH)₂]_n (5), {[Cu(adi)(3-pyaoH)₂]·0.6MeOH·0.3H₂O}_n (6), {[Cu(seb)(3-pyaoH)₂]·H₂seb·H₂O}_n (7), [Cu(ClO₄)(2-pyao)(2-pyaoH)]_n (8), {[Cu(oxa)(2-pyaoH)]·H₂O}_n (9) and {[Cu₃(μ₃-OH)(2-pyao)₃(fum)]·6.5H₂O}_n (10) were obtained by reactions of Cu(ii) salts with binary blends of isomeric pyridine-n-oximes (n-pyaoH, n = 2-4) and dicarboxylic acids (oxalic = H₂oxa, malonic = H₂mal, fumaric = H₂fum, succinic = H₂suc, adipic = H₂adi, and sebacic = H₂seb). Compounds 1-4, and 8, 9 represent chain-type coordination polymers with the single Cu(ii) atom as a metal building block bridged by the inorganic or organic anions while the pyridine-n-oxime ligands occupy the terminal positions and coordinate in the monodentate or bidentate-chelate coordination mode. The extension of structures up to 2D coordination networks in 5-7 is derived from the bidentate-bridging function of the neutral 3-pyaoH ligand acting through the N-pyridine and O-hydroxyl binding sites. A linear coordination polymer 10 is unique in this series bearing trinuclear [Cu₃(μ₃-OH)(2-pyao)₃]²⁺ metallacrown cores bridged by fumarato linkers. The possibility to tune the Cu(ii)⋯Cu(ii) separations in the reported 1D and 2D coordination polymers through coordination and intermolecular H-bonds was demonstrated and discussed.