Anion-assisted Fe(III)-coordination supramolecular systems based on 2,6-diacetylpyridine dihydrazone
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DANILESCU, Olga, BULHAK, Ion, BOUROSH, Pavlina, CROITOR, Lilia. Anion-assisted Fe(III)-coordination supramolecular systems based on 2,6-diacetylpyridine dihydrazone. In: Polyhedron, 2022, nr. 215, p. 0. ISSN 0277-5387. DOI: https://doi.org/10.1016/j.poly.2022.115679
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Polyhedron
Numărul 215 / 2022 / ISSN 0277-5387 /ISSNe 1873-3719

Anion-assisted Fe(III)-coordination supramolecular systems based on 2,6-diacetylpyridine dihydrazone

DOI: https://doi.org/10.1016/j.poly.2022.115679

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Danilescu Olga1, Bulhak Ion1, Bourosh Pavlina12, Croitor Lilia2
 
1 Institute of Chemistry,
2 Institute of Applied Physics
 
Disponibil în IBN: 10 februarie 2022


Rezumat

Six new iron coordination complexes were obtained as a result of the direct interaction of the Fe3+ ion and Schiff base ligands in the presence of anions with weak, moderate and high coordinating ability in order to study their role in the construction of diverse supramolecular assemblies. All the crystalline solids present mononuclear complexes: [Fe(H2L1)(H2O)1.5(MeOH)0.5](ClO4)3·1.75H2O (1), [Fe(H2L2)(H2O)2](ClO4)3·H2O (2), [Fe(HL1)(NCS)2]·0.25H2O (3), [Fe(HL2)(NCS)2]·2.33H2O (4), [Fe(L1)(N3)(H2O)]·H2O (5) and [Fe(L2)(H2O)2]OH·4H2O (6), where H2L1 = 2,6-diacetylpyridine bis(isonicotinoylhydrazone) and H2L2 = 2,6-diacetylpyridine bis(nicotinoylhydrazone), which were characterized by IR spectroscopy and single crystal X-ray diffraction. The Schiff base ligands in the perchlorate-assisted compounds adopt a double zwitterion tautomeric form and these coordinate as neutral ligands. In the isothiocyanate complexes, the Schiff base coordinates as a single zwitterionic monoprotonated ligand, while the presence of the N3 anion in the reaction leads to the bisdeprotonation of both 2,6-diacetylpyridine dihydrazones. The crystal structures of all the coordination compounds show different types of weak intermolecular interactions, which were confirmed by the analysis of their Hirshfeld surfaces and the corresponding fingerprint diagrams. 

Cuvinte-cheie
Anion coordination ability, Fe(III), Intermolecular interactions, Schiff base, Supramolecular assemblies