The design and synthesis of coordination polymers (CP) is attracted the great attentions due to extraordinary properties displayed by this class of materials with potential applications in the range of fields such as catalysis, gas storage and separation, magnetism, photonics, drag delivery. A general strategy for synthesizing coordination polymers involves the use of ridging organic ligands and metal salts to produce a variety of CP with desirable and exceptional properties. A series of coordination polymers by using d-metal ions and different bridging ligands (carboxylates, CN and N-donor ligands) has been prepared (Fig. 1a-d). Other strategy consists of the applications of pre-designed metal carboxylate complexes with available and geometrically well-defined coordination sites to induce the assembly of multi-dimensional structures (Fig. 1e-f). The range of practical uses of these coordination polymers has been expanded by the discovery of their magnetic, photophysical and specific catalytic properties in the oxidation processes.figure Figure 1. Structures of phthalate-bridged linear (a) and zig-zag (b) chains, cyanide-bridged linear (c ) and ladder (d) chains and cluster-based chains in which carboxylate trinuclear (e) and hexanuclear (f) metal units are connected by N-donor ligands.