The non-conventional methods of synthesis belong to green chemistry and offer many advantages. The microwave and ultrasound irradiation, as well as electrochemical and photochemical transformations often lead to desired results through nonspecific mechanisms, reduces the cost, increase yields and exclude the use of reagents, or the formation of toxic reaction products. Since being obtained by the Stoll method from commercially available (+)-sclareolide [1], esters 1-3 have been noted as an important starting material for the synthesis of new compounds or natural analogues from the homodrimanic or drimanic series [2-4]. The disadvantage of this method, however, lies in the too long duration of the transesterification-dehydration reaction (96h). Bicyclohomofarnesenic methyl esters 1-3 and products of their electrochemical and photochemical transformations 4-8. Using microwave irradiation (MeOH, H2SO4, MW, 15'), we managed to obtain compounds 1-3, in just 15 minutes, with the same yield and co-ratio of the products. Further, an exhaustive study of the anodic oxidation reaction of esters 1-3 (LiClO4, MeOH, e, 6h) was performed. Additionally to previously reported compounds 4 and 5 [5], a series of minor compounds 6-8 were isolated from the reaction mixture and characterized (Figure 1). The sensitized photooxidation of esters 1-3 mixture (DCM, TPP, hv, 7h) lead to new isomeric hydroperoxydes 9 and 10. In continuation, by means of standard methods, these compounds were converted in corresponding alcohols and acetates. The structures of all synthetized compounds were fully confirmed by spectral methods of analysis.