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<identifier identifierType='DOI'>10.1039/c9dt00770a</identifier>
<creators>
<creator>
<creatorName>Tupolova, Y.P.</creatorName>
<affiliation>Южный федеральный университет, Ростов-на-Дону, Rusia</affiliation>
</creator>
<creator>
<creatorName>Shcherbakov, I.N.</creatorName>
<affiliation>Южный федеральный университет, Ростов-на-Дону, Rusia</affiliation>
</creator>
<creator>
<creatorName>Popov, L.D.</creatorName>
<affiliation>Южный федеральный университет, Ростов-на-Дону, Rusia</affiliation>
</creator>
<creator>
<creatorName>Lebedev, V.E.</creatorName>
<affiliation>Южный федеральный университет, Ростов-на-Дону, Rusia</affiliation>
</creator>
<creator>
<creatorName>Tkachev , V.V.</creatorName>
<affiliation>Institute of Problems of Chemical Physics, Russian Academy of Sciences, Rusia</affiliation>
</creator>
<creator>
<creatorName>Zakharov, K.V.</creatorName>
<affiliation>Universitatea de Stat M.V. Lomonosov din Moscova, Rusia</affiliation>
</creator>
<creator>
<creatorName>Vasiliev, A.N.</creatorName>
<affiliation>Universitatea de Stat M.V. Lomonosov din Moscova, Rusia</affiliation>
</creator>
<creator>
<creatorName>Korchagin, D.V.</creatorName>
<affiliation>Institute of Problems of Chemical Physics, Russian Academy of Sciences, Rusia</affiliation>
</creator>
<creator>
<creatorName>Palii, A.V.</creatorName>
<affiliation>Institute of Problems of Chemical Physics, Russian Academy of Sciences, Rusia</affiliation>
</creator>
<creator>
<creatorName>Aldoshin, S.M.</creatorName>
<affiliation>Institute of Problems of Chemical Physics, Russian Academy of Sciences, Rusia</affiliation>
</creator>
</creators>
<titles>
<title xml:lang='en'>Field-induced single-ion magnet behaviour of a hexacoordinated Co(ii) complex with easy-axis-type magnetic anisotropy</title>
</titles>
<publisher>Instrumentul Bibliometric National</publisher>
<publicationYear>2019</publicationYear>
<relatedIdentifier relatedIdentifierType='ISSN' relationType='IsPartOf'>1477-9226</relatedIdentifier>
<dates>
<date dateType='Issued'>2019-02-01</date>
</dates>
<resourceType resourceTypeGeneral='Text'>Journal article</resourceType>
<descriptions>
<description xml:lang='en' descriptionType='Abstract'><p>A coordination compound with the composition [CoLCl <sub>2</sub> ]&middot;H <sub>2</sub> O (L = bis-condensation product of diacetyl and 2-hydrazinyl-4,6-dimethylpyrimidine) was synthesized, in which the Co(ii) ion was hexacoordinated. Under applied DC fields, this compound exhibited single-ion magnet behavior. Two relaxation processes were observed when increasing the applied magnetic field from 1000 to 3200 Oe. The first relaxation (high-frequency) was observed both at 1000 Oe and 3200 Oe, while the second relaxation was only registered under a field of 3200 Oe at low frequencies (&lt;1 Hz) and low temperatures (&lt;5 K). Modeling of the magnetic DC properties using the Griffith Hamiltonian accompanied by quantum chemical calculations revealed easy-axis-type magnetic anisotropy with weak rhombic contributions.</p></description>
</descriptions>
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<format>uri</format>
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