Crystal structures of bis[2-({[(ethylsulfanyl)(prop-2-en-1-ylamino) methylidene]hydrazinylidene}methyl)-6-methoxyphenolate]cobalt(III) tetrachlorocobaltat(II)
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PETRENKO, Peter A., CHUMAKOV, Yurii, USATAIA, Irina, GRAUR, Vasilii О., TSAPKOV, Victor I., GULYA, Aurelian. Crystal structures of bis[2-({[(ethylsulfanyl)(prop-2-en-1-ylamino) methylidene]hydrazinylidene}methyl)-6-methoxyphenolate]cobalt(III) tetrachlorocobaltat(II). In: Materials Science and Condensed Matter Physics, Ed. 9, 25-28 septembrie 2018, Chișinău. Chișinău, Republica Moldova: Institutul de Fizică Aplicată, 2018, Ediția 9, p. 145.
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Materials Science and Condensed Matter Physics
Ediția 9, 2018
Conferința "International Conference on Materials Science and Condensed Matter Physics"
9, Chișinău, Moldova, 25-28 septembrie 2018

Crystal structures of bis[2-({[(ethylsulfanyl)(prop-2-en-1-ylamino) methylidene]hydrazinylidene}methyl)-6-methoxyphenolate]cobalt(III) tetrachlorocobaltat(II)

CZU: 546+547

Pag. 145-145

Petrenko Peter A.1, Chumakov Yurii12, Usataia Irina3, Graur Vasilii О.3, Tsapkov Victor I.3, Gulya Aurelian3
 
1 Institute of Applied Physics,
2 Gebze Institute of Technology,
3 Moldova State University
 
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Disponibil în IBN: 5 februarie 2019


Rezumat

S-Alkylisothiosemicarbazones belong to an important class of thiosemicarbazone derivatives. Much attention has been paid to the synthesis, structure and biological properties of coordination compounds with these ligands. Many of these substances possess biological activity. It was found that the biological properties of these complexes correlate with their structures.  The aim of this work is the determination of structural properties of bis[2-({[(ethylsulfanyl)(prop-2-en-1-ylamino)methylidene]hydrazinylidene}methyl)-6-methoxyphenolate]cobalt(III) tetrachloro-cobaltat(II) [Co(L)2]2[CoCl4] (I). The asymmetric unit contains two independent complexes of I and their octahedral volumes are equal to 9.153 and 9.139 Å3. The CoCl4 anion is the outer sphere complex.