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Неорганическая химия (450) |
Органическая химия (484) |
SM ISO690:2012 PETRENKO, Peter A., CHUMAKOV, Yurii, USATAIA, Irina, GRAUR, Vasilii О., TSAPKOV, Victor I., GULYA, Aurelian. Crystal structures of bis[2-({[(ethylsulfanyl)(prop-2-en-1-ylamino) methylidene]hydrazinylidene}methyl)-6-methoxyphenolate]cobalt(III) tetrachlorocobaltat(II). In: Materials Science and Condensed Matter Physics, Ed. 9, 25-28 septembrie 2018, Chișinău. Chișinău, Republica Moldova: Institutul de Fizică Aplicată, 2018, Ediția 9, p. 145. |
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Materials Science and Condensed Matter Physics Ediția 9, 2018 |
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Conferința "International Conference on Materials Science and Condensed Matter Physics" 9, Chișinău, Moldova, 25-28 septembrie 2018 | |||||||
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CZU: 546+547 | |||||||
Pag. 145-145 | |||||||
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S-Alkylisothiosemicarbazones belong to an important class of thiosemicarbazone derivatives. Much attention has been paid to the synthesis, structure and biological properties of coordination compounds with these ligands. Many of these substances possess biological activity. It was found that the biological properties of these complexes correlate with their structures. The aim of this work is the determination of structural properties of bis[2-({[(ethylsulfanyl)(prop-2-en-1-ylamino)methylidene]hydrazinylidene}methyl)-6-methoxyphenolate]cobalt(III) tetrachloro-cobaltat(II) [Co(L)2]2[CoCl4] (I). The asymmetric unit contains two independent complexes of I and their octahedral volumes are equal to 9.153 and 9.139 Å3. The CoCl4 anion is the outer sphere complex. |
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