Studies on the water solubilization processes of oenotannins and their phisico-chemical properties
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DUKA, Gh., LUPASCU, Tudor, VLAD, Pavel, KULCIŢKI, Veaceslav, NASTAS, Raisa. Studies on the water solubilization processes of oenotannins and their phisico-chemical properties . In: Chemistry Journal of Moldova, 2006, nr. 1(1), pp. 60-64. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2006.01(1).01
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Chemistry Journal of Moldova
Numărul 1(1) / 2006 / ISSN 1857-1727 /ISSNe 2345-1688

Studies on the water solubilization processes of oenotannins and their phisico-chemical properties
DOI:https://doi.org/10.19261/cjm.2006.01(1).01

Pag. 60-64

Duka Gh., Lupascu Tudor, Vlad Pavel, Kulciţki Veaceslav, Nastas Raisa
 
Institute of Chemistry of the Academy of Sciences of Moldova
 
 
Disponibil în IBN: 2 decembrie 2013


Rezumat

The results of investigation of oenotannins content in the seeds of different grape varieties are presented in the paper. It was demonstrated that the oenotannins content depends on the grape variety as well as on the eographycal zone of grape cultivation. A new procedure for water sollubilization of oenotannins by depolimerization has been elaborated. The mechanism of the oenotannins depolimerization has been reveiled by masss-spectrometric studies. It has been established, that the depolimerization process brings about formation of carboxilic acids and organic peroxides. The presence of the carboxilic and peroxidic groups was detremined on the basis of IR spectral analysis. It was demonstrated that the antioxidant properties of modified tannins are higher then those of initial unmodified ones.