CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX
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2020-04-18 21:50
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LAZARESKU, Ana, MELNIK, E., SHOVA, Sergiu, KRAVTSOV, Victor, TURTA, Constantin. CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX. In: Chemistry Journal of Moldova, 2015, nr. 1(10), pp. 52-56. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2015.10(1).07
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Chemistry Journal of Moldova
Numărul 1(10) / 2015 / ISSN 1857-1727 /ISSNe 2345-1688

CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX
DOI: https://doi.org/10.19261/cjm.2015.10(1).07

Pag. 52-56

Lazaresku Ana1, Melnik E.2, Shova Sergiu1, Kravtsov Victor2, Turta Constantin1
 
1 Institute of Chemistry of the Academy of Sciences of Moldova,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
Disponibil în IBN: 20 martie 2017


Rezumat

A lanthanum(III) cyanoacetate complex {[La2(CNCH2COO)6 (H2O)4]∙H2O}n (1) was synthesized and characterized by X-ray single-crystal analysis. The complex 1 exhibits one-dimensional coordination polymer structure. Cyanoacetate ligands coordinated in the bidentate bridging and tridentate-chelating bridging modes. The cyano-group of ligand is not coordinated to the lanthanide ion.

Cuvinte-cheie
coordination polymers, crystal structure,

lanthanum (III), cyanoacetic acid