Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
1248 24 |
Ultima descărcare din IBN: 2024-03-01 06:05 |
SM ISO690:2012 GORINCHOY, Viorina, SHOVA, Sergiu, MELNIK, E., KRAVTSOV, Victor, TURTA, Constantin. Homotrinuclear Fe3 III μ – oxo salicylate cluster. Synthesis, structure and properties. In: Chemistry Journal of Moldova, 2013, nr. 2(8), pp. 83-89. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2013.08(2).10 |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
Chemistry Journal of Moldova | ||||||
Numărul 2(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
|
||||||
DOI:https://doi.org/10.19261/cjm.2013.08(2).10 | ||||||
Pag. 83-89 | ||||||
|
||||||
Descarcă PDF | ||||||
Rezumat | ||||||
A reaction of iron and barium nitrate with ammonium salicylate in the mixture of solvents (MeOH, THF, DMAA) gave the new homotrinuclear complex [hexa-μ-salicylato-(O,O’)-μ3-oxo(diaqua)(salicylato)triiron(III)] di(dimethylacetamide) methanol)sesqui(tetrahydrofuran)·2.6-hydrate, [Fe3O(SalH)7(H2O)2](DMAA)2(MeOH) (THF)1.5(H2O)2.6 (1). Single-crystal X-ray study has demonstrated that the titled complex {Fe3O} belongs to the wellknown
group of μ3-oxo homotrinuclear carboxylates. The IR, Mössbauer spectra, thermal behaviour of the complex were studied. |
||||||
Cuvinte-cheie carboxy-cluster, salicylate, Iron(III), IR, Mössbauer |
||||||
|
DataCite XML Export
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xmlns='http://datacite.org/schema/kernel-3' xsi:schemaLocation='http://datacite.org/schema/kernel-3 http://schema.datacite.org/meta/kernel-3/metadata.xsd'> <identifier identifierType='DOI'>10.19261/cjm.2013.08(2).10</identifier> <creators> <creator> <creatorName>Gorincioi (Olednic), V.V.</creatorName> <affiliation>Institutul de Chimie al AŞM, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Şova, S.G.</creatorName> <affiliation>Institutul de Chimie al AŞM, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Melnic, E.I.</creatorName> <affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Kravţov, V.H.</creatorName> <affiliation>Institutul de Fizică Aplicată al AŞM, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Turtă, C.I.</creatorName> <affiliation>Institutul de Chimie al AŞM, Moldova, Republica</affiliation> </creator> </creators> <titles> <title xml:lang='en'>Homotrinuclear Fe3 III μ – oxo salicylate cluster. Synthesis, structure and properties</title> </titles> <publisher>Instrumentul Bibliometric National</publisher> <publicationYear>2013</publicationYear> <relatedIdentifier relatedIdentifierType='ISSN' relationType='IsPartOf'>1857-1727</relatedIdentifier> <subjects> <subject>carboxy-cluster</subject> <subject>Iron(III)</subject> <subject>salicylate</subject> <subject>IR</subject> <subject>Mössbauer</subject> </subjects> <dates> <date dateType='Issued'>2013-07-01</date> </dates> <resourceType resourceTypeGeneral='Text'>Journal article</resourceType> <descriptions> <description xml:lang='en' descriptionType='Abstract'>A reaction of iron and barium nitrate with ammonium salicylate in the mixture of solvents (MeOH, THF, DMAA) gave the new homotrinuclear complex [hexa-μ-salicylato-(O,O’)-μ3-oxo(diaqua)(salicylato)triiron(III)] di(dimethylacetamide) methanol)sesqui(tetrahydrofuran)·2.6-hydrate, [Fe3O(SalH)7(H2O)2](DMAA)2(MeOH) (THF)1.5(H2O)2.6 (1). Single-crystal X-ray study has demonstrated that the titled complex {Fe3O} belongs to the wellknown group of μ3-oxo homotrinuclear carboxylates. The IR, Mössbauer spectra, thermal behaviour of the complex were studied.</description> </descriptions> <formats> <format>application/pdf</format> </formats> </resource>