Homotrinuclear Fe3 III μ – oxo salicylate cluster. Synthesis, structure and properties

Gorinchoy Viorina; Shova Sergiu; Melnik E.; Kravtsov Victor; Turta Constantin

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2024-03-01 06:05

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GORINCHOY, Viorina, SHOVA, Sergiu, MELNIK, E., KRAVTSOV, Victor, TURTA, Constantin. Homotrinuclear Fe3 III μ – oxo salicylate cluster. Synthesis, structure and properties. In: Chemistry Journal of Moldova, 2013, nr. 2(8), pp. 83-89. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2013.08(2).10

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Chemistry Journal of Moldova

Numărul 2(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688

Homotrinuclear Fe3 III μ – oxo salicylate cluster. Synthesis, structure and properties

DOI:https://doi.org/10.19261/cjm.2013.08(2).10

Pag. 83-89

Gorinchoy Viorina¹, Shova Sergiu¹, Melnik E.², Kravtsov Victor², Turta Constantin¹

¹ Institute of Chemistry of the Academy of Sciences of Moldova,
² Institute of Applied Physics, Academy of Sciences of Moldova

Disponibil în IBN: 26 februarie 2014

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A reaction of iron and barium nitrate with ammonium salicylate in the mixture of solvents (MeOH, THF, DMAA) gave the new homotrinuclear complex [hexa-μ-salicylato-(O,O’)-μ3-oxo(diaqua)(salicylato)triiron(III)] di(dimethylacetamide) methanol)sesqui(tetrahydrofuran)·2.6-hydrate, [Fe3O(SalH)7(H2O)2](DMAA)2(MeOH) (THF)1.5(H2O)2.6 (1). Single-crystal X-ray study has demonstrated that the titled complex {Fe3O} belongs to the wellknown group of μ3-oxo homotrinuclear carboxylates. The IR, Mössbauer spectra, thermal behaviour of the complex were studied.

Cuvinte-cheie
carboxy-cluster, salicylate,

Iron(III), IR, Mössbauer

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