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 SM ISO690:2012GORINCHOY, Viorina, SHOVA, Sergiu, MELNIK, E., KRAVTSOV, Victor, TURTA, Constantin. Homotrinuclear Fe3 III μ – oxo salicylate cluster. Synthesis, structure and properties. In: Chemistry Journal of Moldova, 2013, nr. 2(8), pp. 83-89. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2013.08(2).10 |
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| Chemistry Journal of Moldova | ||||||
| Numărul 2(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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| DOI:https://doi.org/10.19261/cjm.2013.08(2).10 | ||||||
| Pag. 83-89 | ||||||
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A reaction of iron and barium nitrate with ammonium salicylate in the mixture of solvents (MeOH, THF, DMAA) gave the new homotrinuclear complex [hexa-μ-salicylato-(O,O’)-μ3-oxo(diaqua)(salicylato)triiron(III)] di(dimethylacetamide) methanol)sesqui(tetrahydrofuran)·2.6-hydrate, [Fe3O(SalH)7(H2O)2](DMAA)2(MeOH) (THF)1.5(H2O)2.6 (1). Single-crystal X-ray study has demonstrated that the titled complex {Fe3O} belongs to the wellknown
group of μ3-oxo homotrinuclear carboxylates. The IR, Mössbauer spectra, thermal behaviour of the complex were studied. |
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| Cuvinte-cheie carboxy-cluster, salicylate, Iron(III), IR, Mössbauer |
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