Effect of chlorine on the conductivity of ZnO:Ga thin films
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KOLIBABA, Gleb, RUSNAC, Dumitru, FEDOROV, Vladimir, MONAICO, Elena. Effect of chlorine on the conductivity of ZnO:Ga thin films. In: Journal of Materials Science: Materials in Electronics, 2021, nr. 13(32), pp. 18291-18303. ISSN 0957-4522. DOI: https://doi.org/10.1007/s10854-021-06371-x
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Journal of Materials Science: Materials in Electronics
Numărul 13(32) / 2021 / ISSN 0957-4522 /ISSNe 1573-482X

Effect of chlorine on the conductivity of ZnO:Ga thin films

DOI:https://doi.org/10.1007/s10854-021-06371-x

Pag. 18291-18303

Kolibaba Gleb1, Rusnac Dumitru21, Fedorov Vladimir3, Monaico Elena4
 
1 Moldova State University,
2 Institute of Applied Physics,
3 Institute of the Electronic Engineering and Nanotechnologies "D. Ghitu",
4 Technical University of Moldova
 
 
Disponibil în IBN: 9 august 2021


Rezumat

An extensive study of the effect of various technological factors on the electrical properties of ZnO thin films obtained by DC magnetron sputtering of ZnO:Ga:Cl ceramic targets on glass substrates has been carried out. The effect of deposition temperature, film thickness, growth rate, background pressure, working gas pressure, preliminary slow-growing and undoped layers, stoichiometric deviation, and Ga and Cl concentrations has been studied. Changes in the growth rate, transparency in the ultraviolet and visible spectral ranges, morphology, crystallinity, and crystallite size have also been analyzed. It has been shown that the effect of co-doping with Cl is most significant at the lowest temperatures, which can decrease the resistivity of the films by 2 times at a deposition temperature of 100 °C. Zinc oxide thin films with a resistivity of 2.5 × 10− 4 Ω⋅cm and a figure of merit of 31 kΩ− 1 have been successfully obtained. A theoretical model taking into account various types of mobile gallium chlorides has been proposed to elucidate the advantage of co-doping with Cl.