Nickel(II) Complexes with Pentane-2,4-dione Bis(4-allylthiosemicarbazone)

Gulya Aurelian; Graur Vasilii О.; Chumakov Yurii; Petrenko Peter A.; Garbuz Olga; Tsapkov Victor I.; Gudumak V.

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GULYA, Aurelian, GRAUR, Vasilii О., CHUMAKOV, Yurii, PETRENKO, Peter A., GARBUZ, Olga, TSAPKOV, Victor I., GUDUMAK, V.. Nickel(II) Complexes with Pentane-2,4-dione Bis(4-allylthiosemicarbazone). In: Russian Journal of General Chemistry, 2020, vol. 90, pp. 111-117. ISSN 1070-3632. DOI: https://doi.org/10.1134/S107036322001017X

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Russian Journal of General Chemistry

Volumul 90 / 2020 / ISSN 1070-3632 /ISSNe 1608-3350

Nickel(II) Complexes with Pentane-2,4-dione Bis(4-allylthiosemicarbazone)

DOI:https://doi.org/10.1134/S107036322001017X

Pag. 111-117

Gulya Aurelian¹, Graur Vasilii О.¹, Chumakov Yurii²³, Petrenko Peter A.², Garbuz Olga¹⁴, Tsapkov Victor I.¹, Gudumak V.⁵

¹ Moldova State University,
² Institute of Applied Physics,
³ Gebze Institute of Technology,
⁴ Institute of Zoology,
⁵ ”Nicolae Testemițanu” State University of Medicine and Pharmacy

Proiecte:

20.80009.8007.03 Noi substanțe cu potențial preventiv și terapeutic în baza compușilor naturali de origine vegetală și a matodelor moderne de sinteză organică

Disponibil în IBN: 14 octombrie 2020

Rezumat

Reaction of pentane-2,4-dione with N-(prop-2-en-1-yl)hydrazinecarbothioamide at a 1: 2 molar ratio in ethanol resulted in the formation of a pyrazole derivative. The latter reacted with nickel perchlorate at a 1: 1 molar ratio to form the nickel complex with pentane-2,4-dione bis(4-allylthiosemicarbazone). The same type of nickel complex was obtained as a result of N-(prop-2-en-1-yl)hydrazinecarbothioamide reaction with pentane-2,4-dione and nickel nitrate at a 2: 1: 1 molar ratio. Antimicrobial, antifungal, antioxidant, and anticancer activities of the obtained compounds were studied.

Cuvinte-cheie
acetylacetone bis(4-allylthiosemicarbazone), anticancer activity, Ni(II) coordination compounds