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SM ISO690:2012 DARII, Mariana. A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core. In: Moldavian Journal of the Physical Sciences, 2019, nr. 1-4(18), pp. 59-64. ISSN 1810-648X. DOI: https://doi.org/10.5281/zenodo.4019773 |
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Moldavian Journal of the Physical Sciences | ||||||
Numărul 1-4(18) / 2019 / ISSN 1810-648X /ISSNe 2537-6365 | ||||||
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DOI:https://doi.org/10.5281/zenodo.4019773 | ||||||
CZU: 539.2+548.4+544 | ||||||
Pag. 59-64 | ||||||
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A new [Mn6O2(O2CCMe3)10(HO2CCMe3)(EtOH)3]∙EtOH hexanuclear mixed-valent coordination compound with a {Mn6O2} core has been synthesized and characterized by single-crystal X-ray diffraction analysis. The central mixed-valence [MnII4MnIII2(M4-O2)]10+ core consists of six Mn centers, two MnIII and four MnII ions, arranged as two edge-sharing flattened Mn4 tetrahedra, with a M4-O2- ion in the center of each tetrahedron. Peripheral ligation is provided by pivalate and ethanol groups |
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