| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 |
 1057 6 |
| Ultima descărcare din IBN: 2022-08-13 13:09 |
 SM ISO690:2012RIJA, Andrei, COROPCEANU, Eduard, BOLOGA, Olga, PRIVALOV, Victor, COVACI (CIOBĂNICĂ), Olga. Studiul spectroscopic al dioximaţilor Co(III) noi sintetizaţi cu anioni polifluorometalici. In: Studia Universitatis Moldaviae (Seria Ştiinţe Reale şi ale Naturii), 2009, nr. 1(21), pp. 152-156. ISSN 1814-3237. |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
| Studia Universitatis Moldaviae (Seria Ştiinţe Reale şi ale Naturii) | ||||||
| Numărul 1(21) / 2009 / ISSN 1814-3237 /ISSNe 1857-498X | ||||||
|
||||||
| Pag. 152-156 | ||||||
|
||||||
 Descarcă PDF |
||||||
| Rezumat | ||||||
It has been carried out the oriented synthesis of the new Co(III) dioxymates with complex anions of fl uorine of type
[Co(DioxH)2L2]nX⋅mH2O, where DioxH- is the radical of dioxime: dimethylglyoxime (DH2), 1,2-ciclohexandionedioxime
(NioxH2); L – aniline (An), thiocarbamide (Thio), pyridine (Py); X – [SbF6]-, [TiF6]2-. The Cо(III) trans-dioximates
form octahedric compounds with pseudomacrocyclic basis and neutral anionic ligand on the apical coordinates. The
formation of the crystal structures is primarily governed by outer-sphere anions [TiF6]2–, [SbF6]- and crystallization water
molecules. |
||||||
|
|
|
|
