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 SM ISO690:2012VITIU (BOLDIŞOR), Aliona, COROPCEANU, Eduard, BOUROSH, Pavlina. New Сu(II) and Co(II) Complexes with 2-Benzoylpyridine: Syntheses and Crystal Structures. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2019, vol. 45, pp. 804-808. ISSN -. DOI: https://doi.org/10.1134/S1070328419110101 |
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  Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
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| Volumul 45 / 2019 / ISSN - /ISSNe 1070-3284 | ||||||
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| DOI:https://doi.org/10.1134/S1070328419110101 | ||||||
| Pag. 804-808 | ||||||
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Two new mononuclear complexes [Cu(Bzpy)2(Cl)2] (I) and [Cо(Bzpy)2(H2O)2](BF4)2 (II) are synthesized by the reactions of 2-benzoylpyridine (Bzpy) with the copper(II) and cobalt(II) salts. It is found by X-ray diffraction analysis (CIF files CCDC nos. 1908081 (I) and 1908080 (II)) that complex I is molecular and complex II is of the ionic type. Two neutral bidentate-chelate N,O-ligands Bzpy are coordinated to the complexing atom in both complexes. The Cl– anions supplement the coordination polyhedra to octahedra in complex I, and the water molecules supplement the coordination polyhedra to octahedra in complex II. The [BF4]– anions in complex II compensate the positive charge of the complex cations and are bound to them by intermolecular hydrogen bonds О–H···F along with electrostatic interactions. |
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DataCite XML Export
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi='http://www.w3.org/2001/XMLSchema-instance' xmlns='http://datacite.org/schema/kernel-3' xsi:schemaLocation='http://datacite.org/schema/kernel-3 http://schema.datacite.org/meta/kernel-3/metadata.xsd'> <identifier identifierType='DOI'>10.1134/S1070328419110101</identifier> <creators> <creator> <creatorName>Vitiu (Boldişor), A.A.</creatorName> <affiliation>Institutul de Fizică Aplicată, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Coropceanu, E.B.</creatorName> <affiliation>Institutul de Chimie, Moldova, Republica</affiliation> </creator> <creator> <creatorName>Bouroş, P.N.</creatorName> <affiliation>Institutul de Fizică Aplicată, Moldova, Republica</affiliation> </creator> </creators> <titles> <title xml:lang='en'>New Сu(II) and Co(II) Complexes with 2-Benzoylpyridine: Syntheses and Crystal Structures</title> </titles> <publisher>Instrumentul Bibliometric National</publisher> <publicationYear>2019</publicationYear> <dates> <date dateType='Issued'>2019-11-01</date> </dates> <resourceType resourceTypeGeneral='Text'>Journal article</resourceType> <descriptions> <description xml:lang='en' descriptionType='Abstract'><p>Two new mononuclear complexes [Cu(Bzpy)<sub>2</sub>(Cl)<sub>2</sub>] (I) and [Cо(Bzpy)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](BF<sub>4</sub>)<sub>2</sub> (II) are synthesized by the reactions of 2-benzoylpyridine (Bzpy) with the copper(II) and cobalt(II) salts. It is found by X-ray diffraction analysis (CIF files CCDC nos. 1908081 (I) and 1908080 (II)) that complex I is molecular and complex II is of the ionic type. Two neutral bidentate-chelate N,O-ligands Bzpy are coordinated to the complexing atom in both complexes. The Cl<sup>–</sup> anions supplement the coordination polyhedra to octahedra in complex I, and the water molecules supplement the coordination polyhedra to octahedra in complex II. The [BF<sub>4</sub>]<sup>–</sup> anions in complex II compensate the positive charge of the complex cations and are bound to them by intermolecular hydrogen bonds О–H···F along with electrostatic interactions.</p></description> </descriptions> <formats> <format>uri</format> </formats> </resource>
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