Comparative study of porosification in InAs, InP, ZnSe and ZnCdS
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MONAICO, Eduard, TIGINYANU, Ion, NIELSCH, Kornelius, URSACHI, Veaceslav, KOLIBABA, Gleb, NEDEOGLO, Dumitru, COJOCARU, Ala, FOLL, Helmut. Comparative study of porosification in InAs, InP, ZnSe and ZnCdS. In: Nanotechnologies and Biomedical Engineering, Ed. 2, 18-20 aprilie 2013, Chișinău. Technical University of Moldova, 2013, Editia 2, pp. 51-55. ISBN 978-9975-62-343-8..
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Nanotechnologies and Biomedical Engineering
Editia 2, 2013
Conferința "International Conference on Nanotechnologies and Biomedical Engineering"
2, Chișinău, Moldova, 18-20 aprilie 2013

Comparative study of porosification in InAs, InP, ZnSe and ZnCdS


Pag. 51-55

Monaico Eduard12, Tiginyanu Ion23, Nielsch Kornelius1, Ursachi Veaceslav4, Kolibaba Gleb5, Nedeoglo Dumitru5, Cojocaru Ala6, Foll Helmut6
 
1 University of Hamburg,
2 Technical University of Moldova,
3 Institute of the Electronic Engineering and Nanotechnologies "D. Ghitu",
4 Institute of Applied Physics, Academy of Sciences of Moldova,
5 Moldova State University,
6 Christian-Albrechts University of Kiel
 
 
Disponibil în IBN: 14 iunie 2019


Rezumat

We report on a comparative study of the pore growth during anodization of a narrow-bandgap III-V compound (InAs), a medium-bandgap III-V one (InP) and wide-bandgap II-VI semiconductors (ZnSe and Zn0,4Cd0,6S). According to the obtained results, the morphology of the porous layers can be controlled by the composition of the electrolyte and the applied electrochemical parameters. It was evidenced that in the narrow bandgap semiconductor InAs it is difficult to control the mechanism of pore growth. Both currentline oriented pores and crystallographically oriented pores were produced in the medium-bandgap material InP. The electrochemical nanostructuring of wide-bandgap semiconductors realized in single crystalline highconductivity samples evidenced only current-line oriented pores. This behavior is explained in terms of difference in the values of electronegativity of the constituent atoms and the degree of ionicity.

Cuvinte-cheie
Anodization, crystallographically oriented pores, current-line-oriented pores, ionicity degree, porous layer.