Synthesis and Crystal Structure of [Co(DmgH) 2 (Thio) 2 ] 2 F[PF 6 ]. The Effect of Fluorine-Containing Co(III) Dioximates on the Physiological Processes of the Microalga Porphyridium cruentum

Coropceanu Eduard; Rudik V.; Cepoi Liliana; Rudi Ludmila; Lozan Vasile; Chiriac Tatiana; Miscu Vera; Bulhak Ion; Kravtsov Victor; Bourosh Pavlina

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COROPCEANU, Eduard, RUDIK, V., CEPOI, Liliana, RUDI, Ludmila, LOZAN, Vasile, CHIRIAC, Tatiana, MISCU, Vera, BULHAK, Ion, KRAVTSOV, Victor, BOUROSH, Pavlina. Synthesis and Crystal Structure of [Co(DmgH) 2 (Thio) 2 ] 2 F[PF 6 ]. The Effect of Fluorine-Containing Co(III) Dioximates on the Physiological Processes of the Microalga Porphyridium cruentum. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2019, vol. 45, pp. 200-207. ISSN -. DOI: https://doi.org/10.1134/S1070328419030059

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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

Volumul 45 / 2019 / ISSN - /ISSNe 1070-3284

Synthesis and Crystal Structure of [Co(DmgH) ₂ (Thio) ₂ ] ₂ F[PF ₆ ]. The Effect of Fluorine-Containing Co(III) Dioximates on the Physiological Processes of the Microalga Porphyridium cruentum

DOI:https://doi.org/10.1134/S1070328419030059

Pag. 200-207

Coropceanu Eduard¹², Rudik V.³, Cepoi Liliana³, Rudi Ludmila³, Lozan Vasile¹, Chiriac Tatiana³, Miscu Vera³, Bulhak Ion¹, Kravtsov Victor⁴, Bourosh Pavlina²⁴

¹ Institute of Chemistry,
² Tiraspol State University,
³ Institute of Microbiology and Biotechnology ,
⁴ Institute of Applied Physics

Disponibil în IBN: 7 mai 2019

Rezumat

Abstract: New fluorine-containing cobalt(III) dioximates [Co(DmgH) ₂ (Thio) ₂ ] ₂ F[PF ₆ ] (I) and [Co(DmgH) ₂ (Sam) ₂ ] ₂ [TiF ₆ ] · 4H ₂ O (II) (DmgH = dimethylglyoxime monoanion, Thio = thiourea, Sam = sulfanilamide) were obtained. The structure of I was determined by X-ray diffraction (CIF file CCDC no. 1852216). The crystals are cubic, space group (Formula Presented.). The octahedral coordination polyhedron of the metal is formed by the N ₄ S ₂ set of donor atoms of two DmgH¯ ligands and two Thio molecules. The effect of compounds I and II and two previously described compounds of this class with fluorine anions, [Co(DmgH) ₂ (Thio) ₂ ] ₂ [TiF ₆ ] · 2H ₂ O (III) and [Co(DmgH) ₂ (An) ₂ ] ₂ [ZrF ₆ ] (IV) (An = aniline), on the physiological processes of the red microalga Porphyridium cruentum was studied. Complex III in concentration of 20 mg/L increased the microalga productivity by 20% and lipid biosynthesis by 17% and can be proposed for biotechnology applications.

Cuvinte-cheie
biomass accumulation, Co(III) dioximatescrystal structure, lipid synthesis, red microalga, Porphyridium cruentum

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