The crystal structure of 2-[hydrazinylidene(phenyl)-methyl]pyridine and 2-[hydrazinylidenemethyl]-6-methoxyphenol
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2019-04-21 11:14
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PETRENKO, Peter; CHUMAKOV, Yurii; RUSNAC, Roman; GULEA, Aurelian. The crystal structure of 2-[hydrazinylidene(phenyl)-methyl]pyridine and 2-[hydrazinylidenemethyl]-6-methoxyphenol. In: Materials Science and Condensed Matter Physics. Ediția a 9-a, 25-28 septembrie 2018, Chișinău. Chișinău, Republica Moldova: Institutul de Fizică Aplicată, 2018, pp. 164-165.
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Materials Science and Condensed Matter Physics
Ediția a 9-a, 2018
Conferința "International Conference on Materials Science and Condensed Matter Physics"
Chișinău, Moldova, 25-28 septembrie 2018

The crystal structure of 2-[hydrazinylidene(phenyl)-methyl]pyridine and 2-[hydrazinylidenemethyl]-6-methoxyphenol


Pag. 164-165

Petrenko Peter1, Chumakov Yurii12, Rusnac Roman3, Gulea Aurelian3
 
1 Institute of Applied Physics,
2 Gebze Institute of Technology, Cayirova,
3 State University of Moldova
 
Disponibil în IBN: 6 februarie 2019


Rezumat

Hydrazones possess diverse biological and pharmacological properties. These compounds contain C=N bond, which easily coordinates with metal ion, and, from the thermodynamic point of view, form a stable metallocycle. The combination of hydrazones with other functional group leads to compounds with unique physical and chemical character. Owing to their biological and pharmacological properties, they are considered important for the synthesis of heterocyclic compounds. The developing of pyridine-hydrazones derivatives is important due to their chelating 165   ability and structural flexibility. The aim of this work is the synthesis of 2-[hydrazinylidene(phenyl)methyl]pyridine (I) and 2-[hydrazinylidenemethyl]-6-methoxyphenol (II) and determination of their crystal structure. In I the dihedral angle of pyridine ring with hydrazin fragment is equal to 86.7° while the dihedral angles of NNC groups with hydrazin rings in I and II are equal to 80.2 and 5.6° respectively.