Azoligands as bridges in macrocyclic dinickel complexes
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2022-08-02 23:19
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LOZAN, Vasile. Azoligands as bridges in macrocyclic dinickel complexes . In: Chemistry Journal of Moldova, 2010, nr. 1(5), pp. 7-23. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 1(5) / 2010 / ISSN 1857-1727 /ISSNe 2345-1688

Azoligands as bridges in macrocyclic dinickel complexes

Pag. 7-23

Lozan Vasile
 
Institutul de Chimie al AŞM
 
 
Disponibil în IBN: 2 decembrie 2013


Rezumat

The coordination chemistry of dinickel macrocyclic hexaamine-dithiophenolate complexes of Robson-type with azoligands is presented in this microreview. All complexes have been characterised by IR-, UV/Vis-spectroscopy, and X-ray crystallography. The bioctahedral transition metal complexes of the type [(L6)Ni2(μ-L')] exhibit a rich coordination chemistry since the active coordination site L' is accessible for a wide range of exogenous coligands.

Cuvinte-cheie
coordination chemistry, structures,

azoligands, nickel macrocyclic complexes, amino-thiopheno- late ligands