Effects of impurity band in heavily doped ZnO:HCl
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KOLIBABA, Gleb, AVDONIN, A., SHTEPLIUK, I., CARAMAN, Mihail, DOMAGAŁA, Jarosław Zbigniew, INCULETS, Ion. Effects of impurity band in heavily doped ZnO:HCl. In: Physica B: Condensed Matter, 2019, vol. 553, pp. 174-181. ISSN -. DOI: https://doi.org/10.1016/j.physb.2018.10.031
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Physica B: Condensed Matter
Volumul 553 / 2019 / ISSN - /ISSNe 0921-4526

Effects of impurity band in heavily doped ZnO:HCl

DOI:https://doi.org/10.1016/j.physb.2018.10.031

Pag. 174-181

Kolibaba Gleb1, Avdonin A.2, Shtepliuk I.234, Caraman Mihail1, Domagała Jarosław Zbigniew5, Inculets Ion1
 
1 Moldova State University,
2 Institute of Physics PAN,
3 Linkoping University,
4 Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine,
5 Institute of Physics, Polish Academy of Science, Warsaw
 
 
Disponibil în IBN: 10 decembrie 2018


Rezumat

A comparative study of properties of ZnO:HCl single crystals obtained by various methods is presented. Characterization by photoluminescence, optical and electrical measurements in the wide temperature range has allowed to analyze the energy spectra of Cl-containing stable defects in ZnO. Presence of shallow Cl donors, deeper donor complexes, incorporating several Cl atoms or stable H-Cl pairs and presence of compensating deep acceptors, attributed to VZnClO centers, are demonstrated. The presence of shallow donor impurity band, as well as strong dependence of its activation energy on the doping level is shown. The controversy of various models for estimation of this dependence is discussed. It is demonstrated, that 90% of this dependence is caused by feature of temperature dependence of Hall coefficient related to conductive impurity band, and a more correct equation for activation energy is suggested. An abnormally low efficiency of neutral impurity scattering of charge carriers and strong optical absorption in the near-IR spectral range are demonstrated and attributed to upper conductive impurity band of negatively charged donors with an extra electron.

Cuvinte-cheie
Carrier transport phenomena, Donor activation energy, Halide vapor transport, Impurity band, zinc oxide