| Conţinutul numărului revistei |
| Articolul precedent |
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 SM ISO690:2012VITIU (BOLDIŞOR), Aliona, COROPCEANU, Eduard, BOUROSH, Pavlina. Crystal structure of Co(III) α-dimethylglyoximates with imidazole. In: Journal of Structural Chemistry, 2017, nr. 3(58), pp. 526-531. ISSN 0022-4766. DOI: https://doi.org/10.1134/S0022476617030131 |
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 Journal of Structural Chemistry |
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| Numărul 3(58) / 2017 / ISSN 0022-4766 | ||||||
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| DOI:https://doi.org/10.1134/S0022476617030131 | ||||||
| Pag. 526-531 | ||||||
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Two new dimethylglyoximate complexes [Co(DmgH)2(Im)Cl] (I) and (ImH)[Co(DmgH2)2Cl2] (II), where DmgH− is the dimethylglyoxime residue and Im is the imidazole molecule, are synthesized. The composition and structure of the crystals are determined from the elemental analysis, IR spectra, and single crystal X-ray diffraction. Complex I is molecular, containing the Im molecule as a coordinated ligand; complex II is of the ionic type with (ImH)+ involved as an outer-sphere organic cation. The mode of component packing in the crystals mainly depends on the imidazole position in the compounds. |
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| Cuvinte-cheie Co(III) dioximatessingle crystal, X-ray diffraction analysisstructural blocksubstitution reactionsynthesis |
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