Crystal field splitting of 5d states and luminescence mechanism in SrAl2O4:Eu2+ phosphor
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NAZAROV, Michael V.; BRIK, Mikhail G.; SPASSKY, Dmitry; TSUKERBLAT, Boris. Crystal field splitting of 5d states and luminescence mechanism in SrAl2O4:Eu2+ phosphor. In: Journal of Luminescence. 2017, nr. 182, pp. 79-86. ISSN 0022-2313.
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Journal of Luminescence
Numărul 182 / 2017 / ISSN 0022-2313

Crystal field splitting of 5d states and luminescence mechanism in SrAl2O4:Eu2+ phosphor


DOI: 10.1016/j.jlumin.2016.10.015
Pag. 79-86

Nazarov Michael V.1, Brik Mikhail G.234, Spassky Dmitry45, Tsukerblat Boris6
 
1 Institute of Applied Physics, Academy of Sciences of Moldova,
2 Chongqing University of Posts and Telecommunications, Chongqing,
3 University of Tartu, Estonia,
4 Jan Dlugosz University in Czestochowa,
5 Lomonosov Moscow State University,
6 Ben-Gurion University of the Negev
 
Disponibil în IBN: 10 iulie 2018


Rezumat

A stoichiometric SrAl2O4:Eu2+nanosized powder was synthesized by combustion method using urea at 500 °C and calcinated at 1000 °C. The measurements of the luminescent properties of SrAl2O4:Eu2+ were carried out; additionally, theoretical study of the crystal field splitting of the Eu2+ 5d levels at two crystallographically different Sr positions in the SrAl2O4 lattice was performed. Two luminescence bands at 450 nm and near 520 nm were observed at lower temperatures. The luminescence mechanism and peculiar temperature dependence of bands intensities are discussed on the basis of the crystal field theory (within the exchange charge model) combined with the vibronic approach. The latter involves the electron vibrational interaction in two kinds of the Eu2+ centers as well as the interaction between these centers in the host lattice. A simplified single-mode model was adopted for each center and the section of the bi-dimensional adiabatic potential of the Eu2+ dimer along an effective “out-of-phase mode” is considered. This original approach qualitatively explains the temperature dependence of the emission bands intensities by the non-radiative redistribution of excitations between two neighboring Eu2+ centers occupying two crystallographically different Sr positions in the SrAl2O4 lattice.

Cuvinte-cheie
Adiabatic approximation, Crystal field splitting of, Eu2+ 5d states, Electron-vibrational couplingluminescence mechanism, SrAl2O4:Eu2+