Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
1143 13 |
Ultima descărcare din IBN: 2018-08-07 14:10 |
SM ISO690:2012 KRAVTSOV, Victor, MALAESTEAN, Yurii, STYNGACH, Evgenia, DUKA, Gh., MAKAEV, Fliur, VAN LEUSEN, Jan, KOGERLER, Paul, HAUSER, J, KRAMER, Karl W, DECURTINS, Silvio, LIU, Shi-Xia, GHOSH, Ashta, GARCIA, Yann, BACA, Svetlana. Hexanuclear Fe(III) wheels functionalized by amino-acetonitrile derivatives. In: Solid State Sciences, 2018, vol. 78, pp. 156-162. ISSN 1293-2558. DOI: https://doi.org/10.1016/j.solidstatesciences.2018.02.015 |
EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
Solid State Sciences | |
Volumul 78 / 2018 / ISSN 1293-2558 /ISSNe 1873-3085 | |
|
|
DOI:https://doi.org/10.1016/j.solidstatesciences.2018.02.015 | |
Pag. 156-162 | |
Vezi articolul | |
Rezumat | |
Three new hexanuclear Fe(III) coordination wheels [Fe6Cl6(L1)6]·5(MeCN) (1), [Na0.5Fe6Cl6(L1)6](N3)0.5·4.5(MeCN) (2), and [Fe6Cl6(L2)6]·2(MeCN) (3) have been synthesized with new prepared amino-acetonitrile derivatives 2-[bis(2-hydroxyethyl)amino]acetonitrile hydrochloride (H2L1) and 3-[bis(2-hydroxyethyl)amino]propanenitrile hydrochloride (H2L2). They were structurally characterized by single-crystal X-ray diffraction. Mößbauer spectroscopy and magnetic susceptibility measurements indicate dominant antiferromagnetic behavior between the Fe(III) centers. |
|
Cuvinte-cheie N, X-ray diffraction, IronMagnetic properties, Mößbauer spectroscopy, O-ligands |
|
|