High-pressure x-ray diffraction study on the structure and phase transitions of the defect-stannite ZnGa2Se4 and defect-chalcopyrite CdGa2S4
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ERRANDONEA, Daniel J.H., KUMAR, Ravhi, MANJON, Francisco Javier, URSAKI, Veacheslav, TIGINYANU, Ion. High-pressure x-ray diffraction study on the structure and phase transitions of the defect-stannite ZnGa2Se4 and defect-chalcopyrite CdGa2S4. In: Journal of Applied Physics, 2008, vol. 104, p. 0. ISSN 0021-8979. DOI: https://doi.org/10.1063/1.2981089
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Journal of Applied Physics
Volumul 104 / 2008 / ISSN 0021-8979 /ISSNe 1089-7550

High-pressure x-ray diffraction study on the structure and phase transitions of the defect-stannite ZnGa2Se4 and defect-chalcopyrite CdGa2S4

DOI: https://doi.org/10.1063/1.2981089

Pag. 0-0

Errandonea Daniel J.H.1, Kumar Ravhi2, Manjon Francisco Javier3, Ursaki Veacheslav4, Tiginyanu Ion4
 
1 Institute of Materials Science, Spain,
2 University of Nevada, Las Vegas,
3 Universitat Politècnica de València,
4 Institute of Applied Physics, Academy of Sciences of Moldova
 
Disponibil în IBN: 6 aprilie 2018


Rezumat

X-ray diffraction measurements on the sphalerite-derivatives ZnGa2 Se4 and CdGa2 S4 have been performed upon compression up to 23 GPa in a diamond-anvil cell. ZnGa2 Se4 exhibits a defect tetragonal stannite-type structure (I 4- 2m) up to 15.5 GPa and in the range from 15.5 to 18.5 GPa the low-pressure phase coexists with a high-pressure phase, which remains stable up to 23 GPa. In CdGa2 S4, we find that the defect tetragonal chalcopyrite-type structure (I 4-) is stable up to 17 GPa. Beyond this pressure a pressure-induced phase transition takes place. In both materials, the high-pressure phase has been characterized as a defect-cubic NaCl-type structure (Fm 3- m). The occurrence of the pressure-induced phase transitions is apparently related with an increase in the cation disorder on the semiconductors investigated. In addition, the results allow the evaluation of the axial compressibility and the determination of the equation of state for each compound. The obtained results are compared to those previously reported for isomorphic digallium sellenides. Finally, a systematic study of the pressure-induced phase transition in 23 different sphalerite-related AB X2 and A B2 X4 compounds indicates that the transition pressure increases as the ratio of the cationic radii and anionic radii of the compounds increases.