Investigating the sensor response of ceria-containing binary metal oxide nanocomposites
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2018-10-23 12:53
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GERASIMOV, Genrikh N., GROMOV, Vladimir F., BELYSHEVA, T. V., IKIM, M. I., SPIRIDONOVA, E., GREKHOV, M., SHAPOCHKINA, Irina, BRYNZARI, Vladimir, TRAKHTENBERG, Leonid. Investigating the sensor response of ceria-containing binary metal oxide nanocomposites. In: Russian Journal of Physical Chemistry A, 2017, vol. 91, pp. 1976-1980. ISSN 0036-0244. DOI: https://doi.org/10.1134/S0036024417100120
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Russian Journal of Physical Chemistry A
Volumul 91 / 2017 / ISSN 0036-0244 /ISSNe 1531-863X

Investigating the sensor response of ceria-containing binary metal oxide nanocomposites

DOI:https://doi.org/10.1134/S0036024417100120

Pag. 1976-1980

Gerasimov Genrikh N.12, Gromov Vladimir F.21, Belysheva T. V.12, Ikim M. I.1, Spiridonova E.12, Grekhov M.3, Shapochkina Irina4, Brynzari Vladimir5, Trakhtenberg Leonid21
 
1 N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences,
2 Karpov Institute of Physics and Chemistry, Moscow,
3 National Research Nuclear University MEPhI, Moscow,
4 Belarusian State University,
5 Moldova State University
 
 
Disponibil în IBN: 7 februarie 2018


Rezumat

The hydrogen sensing performance of ceria-containing nanocrystalline indium and tin oxides is investigated for different concentrations of added ceria. The sensor response of nanocrytsalline In2O3 is considerably enhanced at low CeO2 concentrations. In contrast, low levels of CeO2 cause a substantial drop in the sensor response of SnO2-based composite; at a 3 wt % level of added ceria, its hydrogen sensing ability is almost entirely suppressed. Possible causes of these effects are investigated via X-ray photoelectron spectroscopy (XPS) and X-ray diffraction. XPS data show that additions of CeO2 have different effects on the structure of the base oxides (In2O3 and SnO2), with implications for the hydrogen sensing performance of the composites.

Cuvinte-cheie
Ceria, indium oxide, metal oxide-based nanocomposites, sensing characteristics, tin oxide