CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX
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LAZARESCU, Ana; MELNIC, Elena; SHOVA, Sergiu; KRAVTSOV, Viktor; TURTA, Constantin. CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX. In: Chemistry Journal of Moldova. 2015, nr. 1(10), pp. 52-56. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 1(10) / 2015 / ISSN 1857-1727 /ISSNe 2345-1688

CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX

DOI: 10.19261/cjm.2015.10(1).07
Pag. 52-56

Lazarescu Ana1, Melnic Elena2, Shova Sergiu1, Kravtsov Viktor2, Turta Constantin1
 
1 Institute of Chemistry of the Academy of Sciences of Moldova,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
Disponibil în IBN: 20 martie 2017


Rezumat

A lanthanum(III) cyanoacetate complex {[La2(CNCH2COO)6 (H2O)4]∙H2O}n (1) was synthesized and characterized by X-ray single-crystal analysis. The complex 1 exhibits one-dimensional coordination polymer structure. Cyanoacetate ligands coordinated in the bidentate bridging and tridentate-chelating bridging modes. The cyano-group of ligand is not coordinated to the lanthanide ion.

Cuvinte-cheie
coordination polymers, crystal structure,

lanthanum (III), cyanoacetic acid