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1043 3 |
Ultima descărcare din IBN: 2017-03-17 16:50 |
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546 (512) |
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SM ISO690:2012 COCU, Maria, MANOLE, Ştefan. Coordination compounds of oxovanadium(iv) based on s-methylisothiosemicarbazide as dyes for thermoplastic polymers. In: Chemistry Journal of Moldova, 2015, nr. 2(10), pp. 95-98. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2015.10(2).13 |
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Chemistry Journal of Moldova | ||||||
Numărul 2(10) / 2015 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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DOI:https://doi.org/10.19261/cjm.2015.10(2).13 | ||||||
CZU: 546 | ||||||
Pag. 95-98 | ||||||
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Rezumat | ||||||
The colouring properties of two coordination compounds previously synthesized by us: 8-(1’,2’-naphthyl)1-R-3-methyl-6-thiomethyl-4,5,7-triazanona-1,3,5,7-tetraenato-1,1’-diolato(-)-O1, O1’, N4, N7-vanadyl, where R=CH3 (1), C6H5 (2) have been investigated. These compounds meet the requirements to be used as dyes for thermoplastic polymers. Colouring complexes have a high photostability (7 points), thermostability (>250 °C) and an intensity of colour, which give a low consumption (0.006 to 0.015 g medium tone, 0.020-0.100 g to 100 g polystyrene intense tone and 0.005 to 0.010 g medium tone and 0.015-0.035 g intense tone for 100 g polyethylene). The investigated compounds stained polystyrene and polyethylene in claret-brick. Compound 2 has a higher thermostability (365 °C) than compound 1 (285 °C). |
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Cuvinte-cheie coordination compounds, dyes, oxovanadium(IV), thermoplastic polymer |
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<meta name="citation_title" content="Coordination compounds of oxovanadium(iv) based on s-methylisothiosemicarbazide as dyes for thermoplastic polymers"> <meta name="citation_author" content="Cocu Maria"> <meta name="citation_author" content="Manole Ştefan"> <meta name="citation_publication_date" content="2015/12/14"> <meta name="citation_journal_title" content="Chemistry Journal of Moldova"> <meta name="citation_volume" content="10"> <meta name="citation_issue" content="2"> <meta name="citation_firstpage" content="95"> <meta name="citation_lastpage" content="98"> <meta name="citation_pdf_url" content="https://ibn.idsi.md/sites/default/files/imag_file/95-98_Coordination%20compounds%20of%20oxovanadium%28iv%29%20based%20on%20s-methylisothiosemicarbazide%20as%20dyes%20for%20thermoplastic%20polymers.pdf">