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973 3 |
Ultima descărcare din IBN: 2017-03-17 16:50 |
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546 (505) |
Chimie anorganică (444) |
SM ISO690:2012 COCU, Maria, MANOLE, Ştefan. Coordination compounds of oxovanadium(iv) based on s-methylisothiosemicarbazide as dyes for thermoplastic polymers. In: Chemistry Journal of Moldova, 2015, nr. 2(10), pp. 95-98. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2015.10(2).13 |
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Chemistry Journal of Moldova | |||||
Numărul 2(10) / 2015 / ISSN 1857-1727 /ISSNe 2345-1688 | |||||
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DOI: https://doi.org/10.19261/cjm.2015.10(2).13 | |||||
CZU: 546 | |||||
Pag. 95-98 | |||||
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Rezumat | |||||
The colouring properties of two coordination compounds previously synthesized by us: 8-(1’,2’-naphthyl)1-R-3-methyl-6-thiomethyl-4,5,7-triazanona-1,3,5,7-tetraenato-1,1’-diolato(-)-O1, O1’, N4, N7-vanadyl, where R=CH3 (1), C6H5 (2) have been investigated. These compounds meet the requirements to be used as dyes for thermoplastic polymers. Colouring complexes have a high photostability (7 points), thermostability (>250 °C) and an intensity of colour, which give a low consumption (0.006 to 0.015 g medium tone, 0.020-0.100 g to 100 g polystyrene intense tone and 0.005 to 0.010 g medium tone and 0.015-0.035 g intense tone for 100 g polyethylene). The investigated compounds stained polystyrene and polyethylene in claret-brick. Compound 2 has a higher thermostability (365 °C) than compound 1 (285 °C). |
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Cuvinte-cheie coordination compounds, dyes, oxovanadium(IV), thermoplastic polymer |
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