Conţinutul numărului revistei |
Articolul precedent |
Articolul urmator |
1097 9 |
Ultima descărcare din IBN: 2023-11-22 22:15 |
Căutarea după subiecte similare conform CZU |
544.1 (93) |
Structura chimică a materiei (92) |
SM ISO690:2012 CHIŞCA, Diana, COROBCEANU, Eduard, PETUHOV, Oleg, CROITOR, Lilia. New solvatomorph of tetrakis(μ2-acetato-o,o')-bis(isonicotinamide-n)-di-copper(ii): synthesis, ir, tga and x-ray study. In: Chemistry Journal of Moldova, 2015, nr. 2(10), pp. 33-39. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2015.10(2).03 |
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Chemistry Journal of Moldova | |||||
Numărul 2(10) / 2015 / ISSN 1857-1727 /ISSNe 2345-1688 | |||||
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DOI: https://doi.org/10.19261/cjm.2015.10(2).03 | |||||
CZU: 544.1 | |||||
Pag. 33-39 | |||||
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Dinuclear tetracarboxylato-bridged copper(II) complex, [Cu2(OAc)4(ina)2]·2dmso (1), where OAc- = CH3COO-, ina=isonicotinamide and dmso=dimethylsulfoxide, has been prepared and crystal structure has been determined by single X-ray diffraction. The compound consists of dinuclear units, in which two Cu(II) ions are bridged by four syn,syn-η1:η1:μ-acetato bridges, showing a paddle-wheel cage-type with a square-pyramidal geometry. In the crystal structure, intermolecular N-H···O hydrogen bonds link the molecules into a 1D linear chain. |
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Cuvinte-cheie copper, isonicotinamide, X-ray, paddle-wheel structure |
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