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 SM ISO690:2012BOUROSH, Pavlina, BOLOGA, Olga, SIMONOV, Yurii A., LIPKOWSKI, Janusz. Synthesis and structure of condensation product of dimethylglyoxime on gold matri . In: Moldavian Journal of the Physical Sciences, 2008, nr. 3(7), pp. 382-388. ISSN 1810-648X. |
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| Moldavian Journal of the Physical Sciences | |
| Numărul 3(7) / 2008 / ISSN 1810-648X /ISSNe 2537-6365 | |
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| Pag. 382-388 | |
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| Rezumat | |
Complex of gold of the composition [AuL(NO2)] (1), where HL is a new tridentate
ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the
matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was
shown that in the system H[AuCl4]
. 4Н2О H2DMG Py, depending on pH of the reaction
medium and sequence of addition of components, the final products have unexpected compositions ([AuIII
(DMG)ClPy], [AuCl2Py2][AuCl4]
.
2[AuCl3Py] or [AuII
L(NO2)]). Molecular
complex 1 is sustained by the Au....Au…Au intermolecular nteractions. |
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