Peierls structural transition in quasi-one-dimensional organic crystals
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2022-03-20 12:53
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ANDRONIC, Serghei, KASIYAN, Anatolie. Peierls structural transition in quasi-one-dimensional organic crystals . In: Moldavian Journal of the Physical Sciences, 2013, nr. 3-4(12), pp. 192-198. ISSN 1810-648X.
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Moldavian Journal of the Physical Sciences
Numărul 3-4(12) / 2013 / ISSN 1810-648X /ISSNe 2537-6365

Peierls structural transition in quasi-one-dimensional organic crystals

Pag. 192-198

Andronic Serghei, Kasiyan Anatolie
 
Technical University of Moldova
 
 
Disponibil în IBN: 19 martie 2014


Rezumat

Peierls transition in quasi-one-dimensional organic crystals of tetrathiofulvalene-tetracyanoquinodimethane (TTF-TCNQ) type is studied in the case where the conduction band is half filled and Fermi dimensionless quasi momentum kF = π/2 and where the concentration of conduction electrons is reduced and the band is filled up to a quarter of the Brillouin zone, kF = π/4. In the physical model of the crystal, it was simultaneously taken into account two the most important interactions of conduction electrons with the longitudinal acoustic phonons. The dispersion equation for renormalized phonons was deduced and solved numerically. The phonon frequency dependences on quasi momentum projection along molecular wires were calculated for different temperatures. The critical temperature of transition was determined.